Co-ordination compounds practice · Medium

The number of water molecule(s) directly bonded to the metal centre in $\mathrm{CuS}{\mathrm{O}_4}\mathrm{\;}.5{\mathrm{H}_2}\mathrm{O\;}$ is

A cobaltamine has the formula ${Co}\left({NH}_3\right)_6 {Cl}_3$, with ${AgNO}_3$ solution, one third of the chloride is precipitated. The complex shows cis-trans isomerism. It can have the structure-

The correct IUPAC name for $\left[ {Cr{{\left( {en} \right)}_2}{F_2}} \right]Cl$ is

The solution of the complex $\left[{Cu}\left({NH}_3\right)_4\right] {SO}_4$ in water will

Which of the following complex species is not expected to exhibit optical isomerism

Coordination number $(\mathrm{CN})$ of a metal ion in a complex can be defined as

Assertion (A) Complexes of $\mathrm{MX}_6$ and $\mathrm{MX}_3 \mathrm{L}$ type (X and $\mathrm{L}$ are unidentate) do not show geometrical isomerism.

Reason (R) Geometrical isomerism is not shown by complexes of coordinate number -6 .

Which of the following is bidentate ligand?

Complex compound $\left[\mathrm{Co}(\mathrm{SCN})_2\left(\mathrm{NH}_3\right)_4\right] \mathrm{Cl}$ does not exhibit:

Assertion: The ligands nitro and nitrito are called ambidentate ligands.

Reason: These ligands give linkage isomers.

Among the following metal carbonyls, $\mathrm{C} - \mathrm{O}$ bond order is lowest in

Which of the following statements is not correct?

The IUPAC name of $\mathrm{K}_3\left[\operatorname{Ir}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]$ is

Assertion: $\left({Ph}_3 P\right)_3 {RhCl}$ is Wilkinson's catalyst.
Reason: $\left({Ph}_3 {P}\right)_3 {RhCl}$ can show optical isomerism but does not show geometrical isomerism.

Spin only magnetic moment of which complex is highest?

Which of the following complex has highest $\mathrm{C}-\mathrm{O}$ bond energy?

Which of the following ligand is tridentate type?

Consider the following statements
I. Chain and position isomerism are not possible together between two isomers
II. Tautomerism is a chemical phenomenon which is catalysed by acid as well as base
III. Tautomers are always metamers
IV. Tautomers are always functional isomers
Select the correct answer by using the codes given below

Coordination number of $\mathrm{Co}$ in the complex $\left[\mathrm{Co}(\mathrm{en})_3\right]^{3 *}$ is

Which of the following complexes will have four different isomers?

Which of the following is not correctly matched?

$\begin{array}{cccccccccccccccccccc} {}&{{\text{Coordination}}\,{\text{polyhedron}}}&{{\text{Shape}}} \\ {{\text{(A)}}}&{{{{\text{[Co(N}}{{\text{H}}_{\text{3}}}{{\text{)}}_{\text{6}}}{\text{]}}}^{{\text{3 + }}}}}&{{\text{Octahedral}}} \\ {{\text{(B)}}}&{{\text{[Ni(CO}}{{\text{)}}_{\text{4}}}{\text{]}}}&{{\text{Square}}\,{\text{planar}}} \\ {{\text{(C)}}}&{{{{\text{[PtC}}{{\text{l}}_{\text{4}}}{\text{]}}}^{{\text{2 - }}}}}&{{\text{Tetrahedral}}} \end{array}$

Amongst the following statements.

I: The structure of $\left[\mathrm{BrF}_4\right]^{+}$ is regular tetrahedral

II: Bond order of $\mathrm{O}_2$ decreases by the removal of an electron

III: $\mathrm{Br}_3^{-}$ and $\mathrm{Br}_3^{+}$ are having same shape and same structure

IV Hybrid orbital of P in $\mathrm{PCl}_5$ is $\mathrm{sp}^3 \mathrm{d}_{\mathrm{xy}}$.

The incorrect statements is/ are

Which of the following is false?

Assertion :- Organic compounds which do not contain chiral carbon atoms can be optically
active.

Reason :-Presence of chiral carbon is an essential condition for optical activity.

The $\left[{Fe}({CN})_6\right]^{3-}$ complex ion

Wrong match is

The crystal field stabilization energy (CFSE) is highest for

Statement I: Under the influence of a strong field ligand, $d^7$-system will have only one unpaired electron either in coordination number six or four

Statement II: $\mathrm{t}_{2 \mathrm{~g}}{ }^6 \mathrm{e}_{\mathrm{g}}{ }^1$ is the electronic configuration for both cases

The most stable ion is

According to valence bond theory which of the following statement is correct about the complexes ${Ni}({CO})_4$ and $\left[{Ni}({CN})_4\right]^{2-}$ if both are diamagnetic in nature