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In the sequence of reactions given above, compounds and are respectively
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JEE • CHEMISTRY • P-BLOCK ELEMENTS
P-block elements practice · Medium
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301
Medium
301 of 320
Understanding
+4 | -1
Consider the following reaction :
Soda extract+ dilute Brown layer. The element confirmed in this test can be:
Soda extract+ dilute Brown layer. The element confirmed in this test can be:
View answer and explanation
Correct option: B
Br
Option B is correct because the reaction sequence described is a test for bromide ions, where chlorine oxidizes bromide to bromine, which forms a brown layer in .
302
Medium
302 of 320
Analyzing
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Among the following which is most likely unhybridized molecule?
View answer and explanation
Correct option: C
Option C (PH3) is correct because phosphorus in PH3 has a very small electronegativity difference with hydrogen, resulting in minimal hybridization.
303
Medium
303 of 320
Understanding
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In the sequence of reactions given above, compounds and are respectively
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Correct option: D
Option D is correct because reacts with water to form , and upon strong heating, it dehydrates to form .
304
Medium
304 of 320
Understanding
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Which among the following is the most reactive?
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Correct option: D
Option D (ICl) is correct because interhalogen compounds like ICl are more reactive than homonuclear diatomic halogens due to the polarity of the bond between the different halogen atoms.
305
Medium
305 of 320
Remembering
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Which one of the following reacts with glass?
View answer and explanation
Correct option: B
HF
Option B (HF) is correct because hydrofluoric acid reacts with silica in glass.
306
Medium
306 of 320
Understanding
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Which of the following is INCORRECT?
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Correct option: D
Purely Basic Oxide
Option D ( Purely Basic Oxide) is correct because is amphoteric, not purely basic.
307
Medium
307 of 320
Remembering
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The function of in the contact process is
View answer and explanation
Correct option: A
To remove arsenic impurity
Option A (To remove arsenic impurity) is correct because is used to adsorb and remove arsenic impurities in the contact process for sulfuric acid production.
308
Medium
308 of 320
Analyzing
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Assertion: is a liquid while is a gas
Reason: There is stronger intermolecular hydrogen bonding in .
Reason: There is stronger intermolecular hydrogen bonding in .
View answer and explanation
Correct option: C
Assertion is correct, but reason is wrong statement.
Option C (Assertion is correct, but reason is wrong statement) is correct because water is a liquid due to strong intermolecular hydrogen bonding, while hydrogen sulfide is a gas due to weaker van der Waals forces.
309
Medium
309 of 320
Analyzing
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Assertion (A) : Structure of is identical for .
Reason (R) : Sulphur atoms in are in different oxidation states.
Reason (R) : Sulphur atoms in are in different oxidation states.
View answer and explanation
Correct option: B
Both and are true but is not the correct explanation of .
Option B is correct. Both the assertion and reason are true, but the reason does not explain why the structures are identical. The identical structure arises from similar bonding and hybridization.
310
Medium
310 of 320
Remembering
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Antimony dissolves in aquaregia to give:
View answer and explanation
Correct option: C
Option C () is correct because Antimony dissolves in aquaregia to give .
311
Medium
311 of 320
Analyzing
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Assertion (A): is planar while is pyramidal.
Reason (R): in is hybridized but in it is -hybridized.
Reason (R): in is hybridized but in it is -hybridized.
View answer and explanation
Correct option: A
Both (A) and (R) are true and (R) is the correct explanation of (A)
Option A (Both (A) and (R) are true and (R) is the correct explanation of (A)) is correct because the planar structure of NO is due to sp hybridization, while the pyramidal structure of NH is due to sp hybridization.
312
Medium
312 of 320
Understanding
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Assertion (A): As to , there is only a small increase in covalent radius.
Reason (R): and/or -orbitals are completely filled in heavier elements.
Reason (R): and/or -orbitals are completely filled in heavier elements.
View answer and explanation
Correct option: A
Both and are correct; is the correct explanation of .
Option A (Both and are correct; is the correct explanation of ) is correct because the small increase in covalent radius from As to Bi is due to the poor shielding effect of the filled d and f orbitals in Bi.
313
Medium
313 of 320
Remembering
+4 | -1
On passing ammonia gas through a reagent ' ', brown precipitate is observed that confirms the presence of ion. The reagent ' ' is:
View answer and explanation
Correct option: A
Nessler's reagent
Option A (Nessler's reagent) is correct because Nessler's reagent reacts with ammonia gas to form a brown precipitate, confirming the presence of NH4+ ions.
314
Medium
314 of 320
Analyzing
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Statement I: The coordination number of ' ' is seldom, if ever 5 where as that of , which is in the same group, is 5 in a large number of compounds
Statement II: The first IE of nitrogen is more than that of
Statement II: The first IE of nitrogen is more than that of
View answer and explanation
Correct option: B
Statement I and statement II are correct but statement II is not the correct explanation of statement I
Option B (Statement I and statement II are correct but statement II is not the correct explanation of statement I) is correct because both statements are factually true, but the ionization energy of nitrogen does not explain its lower coordination number compared to phosphorus.
315
Medium
315 of 320
Analyzing
+4 | -1
In the reaction,
The correct option regarding is/are
The correct option regarding is/are
View answer and explanation
Correct option: D
All of the above
Option D (All of the above) is correct because SnCl2 is a strong reducing agent, an angular molecule, and used as a reagent in the test of Hg2+ radical.
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316
Medium
316 of 320
Understanding
+4 | -1
Thermally most stable compound is
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Correct option: A
Option A () is correct because the thermal stability of oxyacids of chlorine increases with the oxidation state of chlorine; has chlorine in the +7 oxidation state, making it the most stable.
317
Medium
317 of 320
Understanding
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Which one is not an acid salt?
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Correct option: A
Option A () is correct because is a monobasic acid, meaning it only has one replaceable hydrogen atom, and thus cannot form an acid salt with two ions.
318
Medium
318 of 320
Understanding
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Choose the correct statements about the hydrides of group 15 elements.
A. The stability of the hydrides decreases in the order
B. The reducing ability of the hydride increases in the order
C. Among the hydrides, is strong reducing agent while is mild reducing agent.
D. The basicity of the hydrides increases in the order
Choose the most appropriate from the option given below
A. The stability of the hydrides decreases in the order
B. The reducing ability of the hydride increases in the order
C. Among the hydrides, is strong reducing agent while is mild reducing agent.
D. The basicity of the hydrides increases in the order
Choose the most appropriate from the option given below
View answer and explanation
Correct option: B
A and B only
Option B (A and B only) is correct because the stability and reducing ability trends are accurate, while basicity decreases down the group and NH3 is not a strong reducing agent.
319
Medium
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Remembering
+4 | -1
A hybrid rocket propellant uses
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Correct option: A
A liquid oxidizer and a solid fuel
The correct answer is A (A liquid oxidizer and a solid fuel) because hybrid rocket propellants typically use a liquid oxidizer and a solid fuel for combustion.
320
Medium
320 of 320
Understanding
+4 | -1
reacts with to form:
View answer and explanation
Correct option: D
Option D is correct. HI is a strong reducing agent and reduces HNO3 to NO2, while HI itself gets oxidized to I2.
Revision notes and key takeaways
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