Amines practice · Medium

In sodium fusion test of organic compounds, the nitrogen of the organic compound is converted into

Ethylamine is heated with ${CS}_2$ in the presence of ${HgCl}_2$. The product formed is

Which of the following groups does not decrease the basic strength of aniline?

Which of the following will produce isopropyl amine-

$({{I) (C}}{{{H}}_3}{)_2}CO\xrightarrow{{N{H_2}OH}}X\xrightarrow{{LiAl{H_4}}}$

$({{II) C}}{{{H}}_3} - C{H_2} - CHO\xrightarrow[{heat}]{{N{H_3}}}X\xrightarrow{{LiAl{H_4}}}$

$({{III) (C}}{{{H}}_3}{)_2}CH - OH + PC{l_5} \to X\xrightarrow{{N{H_3}}}$

$({{IV) C}}{{{H}}_3} - C{H_2} - C{H_2} - N{H_2}\xrightarrow{{heat}}$

Name the product(s) formed during the reaction of primary aliphatic amines with nitrous acid at room temperature?

Ceric ammonium nitrate and $CHC{l_3}/alc.\,KOH$ are used for the identification of functional groups present in ….. and …… respectively.

Hinsber’s reagent does not react with

The test that is done for the differentiation of primary amines from secondary and tertiary amine is:

An aliphatic amine on treatment with alcoholic carbon disulphide and mercuric chloride forms isothiocyanate, the reaction is known as

When aniline reacts with oil of bitter almonds $\left({C}_6 {H}_5 {CHO}\right)$ condensation takes place and benzal derivative is formed. This is known as

Why are amines less acidic than alcohols of comparable molecular masses?

${C_3}{H_9}N$ cannot represent:

Acetamide and ethylamine can be distinguished by reacting with

What would be the side products formed with primary amine in the Hofmann bromamide degradation reaction?

A gaseous carbon compound is soluable in dilute $\mathrm{HCI}$. The solution on treating with $\mathrm{NaN}{\mathrm{O}_2}$ gives off nitrogen leaving behind a solution which smells of wood spirit. The carbon compound is

Among the following, the strongest base is:

Nitrobenzene on reduction with $Al - Hg$ and water gives:

Given below are two statements:

Statement I: Aniline does not undergo Friedel-Crafts alkylation reaction.

Statement II: Aniline cannot be prepared through Gabriel synthesis.

In the light of the above statements, choose the correct answer from the options given below:

A biodegradable polyamide can be made from

$p -$chloroaniline and anilium hydrochloride can be distinguished by:

Assertion: Amines are more basic than esters and ethers.

Reason: Nitrogen is less electronegative than oxygen. It is in better position to accommodate the positive charge on the proton.

The reduction of $\mathrm{C}{\mathrm{H}_3}\mathrm{CN\;}\,\,\mathrm{to}\,\mathrm{\;C}{\mathrm{H}_3}\mathrm{C}{\mathrm{H}_2}\mathrm{N}{\mathrm{H}_2}\mathrm{\;}$ is called:

Statement-I : $1^\circ, 2^\circ$ and $3^\circ$ amines are hydrogen bonding donors, while $1^\circ$ and $2^\circ$ amines are hydrogen bonding acceptors.

Statement-II: Low molecular weight amines are soluble in water.

The alkyl or benzyl halide on reaction with an ethanolic solution of ammonia yield a product via

Which of the following is the most basic?

$C{H_3}N{H_2}\;$ is heated with sodium and extracted with water and then $AgN{O_3}$ is added. The white ppt. obtained is of:

The gas evolved when methyl amine reacts with nitrous acid is

In the given reaction what will be the product

$R - NH - \mathop C\limits^{\begin{array}{cccccccccccccccccccc} O \\ {||} \end{array}} - H\xrightarrow[{Pyridine}]{{POC{l_3}}}{\text{Product}}$

Choose the correct option from the following.

Assertion: In order to convert $R-Cl$ to pure $R-NH_2,$ Gabriel phthalimide synthesis can be used.

Reason: With proper choice of alkyl halides, phthalimide synthesis can be used to prepare $1^\circ, 2^\circ$ or $3^\circ$ amines.