JEE CHEMISTRY MCQ: AMINES

1 Medium

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Analyzing +4 | -1

p -

chloro aniline and anilinium hydrogen chloride can be distinguished by

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Correct option: D

\mathrm{AgN}{\mathrm{O}_3}

Option D (

\mathrm{AgN}{\mathrm{O}_3}

) is correct because anilinium hydrogen chloride reacts with

\mathrm{AgN}{\mathrm{O}_3}

to give a white precipitate of AgCl, while p-chloroaniline does not.

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\mathrm{Z}

' in the sequence

{{\text{C}}_6}{{\text{H}}_5}{\text{N}}{{\text{H}}_2}\xrightarrow{{{\text{NaN}}{{\text{O}}_2} + {\text{HCl}}}}{\text{X}}\xrightarrow{{{\text{CuCN}}}}{\text{Y}}\xrightarrow{{{{\text{H}}^ + }/{{\text{H}}_2}{\text{O}}}}{\text{Z}}

The primary, secondary and tertiary amines can be distinguished by: Assertion: The main product of reaction of alcoholic silver nitrite and ethyl bromide is nitroethane.

Reason: Silver nitrite is predominantly covalent compound. Hofmann’s bromamide reaction is to convert Gabriel phthalamide synthesis is used for preparation of :- Elements found in explosive are: