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NEET • CHEMISTRY • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES
Organic chemistry-some basic principles and techniques practice · Mixed difficulty
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241
Medium
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Remembering
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Least stable conformer of cyclohexane is
View answer and explanation
Correct option: D
Planar hexagon
Option D is correct because the planar hexagon is the least stable conformer of cyclohexane due to significant angle strain and torsional strain. The chair form is the most stable.
242
Medium
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Application
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The maximum number of possible optical isomers in 1-bromo-2-methyl cyclobutane is
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Correct option: A
4
Option A (4) is correct because 1-bromo-2-methyl cyclobutane has two chiral centers, leading to a maximum of 2^n = 22 = 4 stereoisomers.
243
Medium
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Analyzing
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Statement-I: In group III metal ion analysis we should not use only without saturating by .
Statement-II: In the highly alkaline solution and both precipitated together.
Statement-II: In the highly alkaline solution and both precipitated together.
View answer and explanation
Correct option: C
If Statement-I is true but Statement-II is false
Option C (If Statement-I is true but Statement-II is false) is correct because Statement-I is true, but Statement-II is false.
244
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Remembering
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In Duma’s method for determining the nitrogen content of an organic compound, the nitrogen content is determined in the form of:
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Correct option: C
Gaseous
Option C (Gaseous ) is correct because in Duma's method, the nitrogen content is determined by collecting and measuring the volume of nitrogen gas produced.
245
Medium
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Understanding
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Carbanion can undergo :
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Correct option: D
All of the above are correct
Option D (All of the above are correct) is correct because carbanions are capable of rearrangement, combination with cations, and addition to carbonyl groups due to their negative charge and electron-rich nature.
246
Easy
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Remembering
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Rotation of plane polarized light can be measured by :
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Correct option: C
Polarimeter
Option C is correct because the rotation of plane-polarized light can be measured by a polarimeter. A polarimeter is specifically designed for this purpose.
247
Easy
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Remembering
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The tautomeric form which is less stable is called :
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Correct option: C
Labile form
Option C (Labile form) is correct because the labile form in tautomerism refers to the less stable tautomer.
248
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Understanding
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Unpaired electron in occupies:
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Correct option: B
- hybrid orbital
Option D ( - hybrid orbital) is correct because the methyl radical has three sigma bonds and one unpaired electron, resulting in hybridization.
249
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Understanding
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Which of the organic compounds will give red colour in Lassaigne test?
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Correct option: B
Option A () is correct because in the Lassaigne's test, if both nitrogen and sulfur are present, they combine to form NaCNS, which reacts with to form a blood-red color.
250
Hard
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Understanding
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Geometrical isomerism is not shown by
View answer and explanation
Correct option: A
1, 1-dichloro-1-pentene
Option A (1, 1-dichloro-1-pentene) is correct because geometrical isomerism requires different groups on each carbon of the double bond, and this compound has two identical chlorine atoms on one carbon.
251
Medium
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Application
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At low temperature, the slow addition of molecular bromine to gives:
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Correct option: C
Option B () is correct because at low temperature, bromine adds to the alkene first, as alkynes are less reactive than alkenes towards electrophilic addition.
252
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Understanding
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The stability of 2,3-dimethyl but-2-ene is more than 2-butene. This can be explained in terms of :
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Correct option: B
Hyperconjugation
Option B (Hyperconjugation) is correct because 2,3-dimethylbut-2-ene has more alpha hydrogens than 2-butene, leading to greater stabilization through hyperconjugation.
253
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Understanding
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A molecule is . If H is replaced by and on doing so electron density on part increases, then Z is :
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Correct option: C
Electron repelling group
Option C (Electron repelling group) is correct because if the electron density on increases when H is replaced by Z, then Z must be donating electrons, thus repelling them.
254
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Analyzing
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Which technique among the following, is most appropriate in separation of a mixture of of -nitrophenol and picric acid?
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Correct option: D
Preparative TLC (Thin Layer Chromatography)
Option D (Preparative TLC (Thin Layer Chromatography)) is correct because it is suitable for separating small amounts of compounds with different polarities.
255
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Remembering
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Inductive effect involves
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Correct option: A
Displacement of - Electrons
Option A (Displacement of - Electrons) is correct because the inductive effect involves the displacement of sigma electrons along a chain.
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256
Easy
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Remembering
+4 | -1
The first organic compound urea was synthesized in the laboratory by:
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Correct option: D
Wöhler
Option D (Wöhler) is correct because Friedrich Wöhler synthesized urea in the laboratory, disproving the vitalism theory.
257
Easy
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Analyzing
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Among the following, which one has more than one kind of hybridization?
(i)
(ii)
(iii)
(iv) CH ≡ CH
(i)
(ii)
(iii)
(iv) CH ≡ CH
View answer and explanation
Correct option: A
(ii) and (iii)
Option A ((ii) and (iii)) is correct because in (ii) there are both and hybridized carbons, and in (iii) there are , and hybridized carbons.
258
Easy
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Understanding
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Identify which of the following group act as as well as ?
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Correct option: B
Option B () is correct because chlorine can act as both a +M and -I group due to its lone pairs and electronegativity, but its +M effect is weaker than its -I effect.
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Medium
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Remembering
+4 | -1
A Dewar flask is usually used to:
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Correct option: D
Store liquid air
The correct answer is Store liquid air because Dewar flasks are designed to minimize heat transfer, making them ideal for storing cryogenic liquids like liquid air.
260
Hard
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Analyzing
+4 | -1
Total number of isomeric aldehydes and ketones that can exist with the molecular formula :
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Correct option: D
7
Option D (7) is correct because there are 7 isomeric aldehydes and ketones with the molecular formula .
261
Easy
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Understanding
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The isomerism which exists between and is :
View answer and explanation
Correct option: C
Positional
Option C (Positional) is correct because the compounds have the same molecular formula but differ in the position of the chlorine atoms on the carbon chain.
262
Hard
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Analyzing
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Which statement is true?
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Correct option: D
By breaking two bonds on the chiral centre configuration changes
Option D is correct because breaking two bonds on a chiral center will change the spatial arrangement of the remaining groups, thus altering the configuration.
263
Hard
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Understanding
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Which of the following would yield a carbon radical on heating?
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Correct option: B
Option B (Et4Pb) is correct because tetraethyllead (Et4Pb) is known to decompose upon heating, generating ethyl radicals.
264
Easy
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Remembering
+4 | -1
The relative adsorption of each component of the mixture is expressed in terms of
View answer and explanation
Correct option: B
retention factor
The correct answer is retention factor because it quantifies the relative migration of a substance in chromatography.
265
Medium
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Understanding
+4 | -1
Which of the following statements is correct?
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Correct option: A
Allyl carbonium ion is more stable then propyl carbonium ion
Option B () is correct because but-1-ene-3-yne has 7 sigma bonds and 3 pi bonds when you draw out its structure and count them.
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Medium
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Understanding
+4 | -1
The IUPAC name of
View answer and explanation
Correct option: A
Propanal-1
Option A (Propanal-1) is correct because the aldehyde group is always at the end of the chain (carbon 1), and the parent chain is propane.
267
Medium
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Application
+4 | -1
Total isomers with the molecular formula, is
View answer and explanation
Correct option: C
8
Option C (8) is correct because there are eight structural isomers of C4H11N, considering different arrangements of the carbon chain and the amine group.
268
Medium
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Understanding
+4 | -1
A molecule having three different chiral carbon atoms, how many stereoisomers it will have?
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Correct option: A
8
Option A (8) is correct because the number of stereoisomers is given by , where n is the number of chiral centers. Here, n=3, so .
269
Hard
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Understanding
+4 | -1
The halogen compound which most readily undergoes nucleophilic substitutions is
View answer and explanation
Correct option: D
Option D () is correct because the allylic halide is more reactive towards nucleophilic substitution due to the stability of the resulting carbocation by resonance.
270
Medium
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Understanding
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Given below are two statements.
Statement I: The presence of weaker bonds make alkenes less stable than alkanes.
Statement II: The strength of the double bond is greater than that of carbon-carbon single bond.
In the light of the above statements, choose the correct answer from the options given below.
Statement I: The presence of weaker bonds make alkenes less stable than alkanes.
Statement II: The strength of the double bond is greater than that of carbon-carbon single bond.
In the light of the above statements, choose the correct answer from the options given below.
View answer and explanation
Correct option: A
Both Statement I and Statement II are correct.
Option A (Both Statement I and Statement II are correct) is correct because alkenes are indeed less stable due to weaker pi bonds, and the overall double bond strength is greater than a single bond.
Revision notes and key takeaways
Review ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES in your textbook or class notes, then use this set to check your understanding.
Showing 241-270 of 392 questions
