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NEET • CHEMISTRY • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES
Organic chemistry-some basic principles and techniques practice · Mixed difficulty
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301
Medium
301 of 392
Understanding
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Which of the following compounds will show metamerism?
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Correct option: B
Option B () is correct because metamerism requires different alkyl groups attached to the same functional group, which is possible with sulfur.
302
Hard
302 of 392
Remembering
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An indicator ‘’ is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with at room temp. The indicator ‘’ forms blue colored complex with
compound ‘’ present in the solution. The indicator ‘’ and compound ‘’ respectively are
compound ‘’ present in the solution. The indicator ‘’ and compound ‘’ respectively are
View answer and explanation
Correct option: B
Starch and iodine
The correct answer is Starch and iodine because starch forms a blue-colored complex with iodine in solution, which is used as an indicator in redox titrations.
303
Hard
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Understanding
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False statement is
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Correct option: C
Diastereomers have identical physical properties
Option C (Diastereomers have identical physical properties) is the false statement because diastereomers have different physical properties.
304
Easy
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Remembering
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Isomerism among compounds due to the migration of a proton is known as :
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Correct option: C
Tautomerism
Option C is correct because tautomerism involves the migration of a proton, resulting in two interconvertible structural isomers.
305
Easy
305 of 392
Understanding
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Different structures generated due to rotation about, C – C axis, of an organic molecule, are examples of
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Correct option: B
Conformational isomerism
Option B (Conformational isomerism) is correct because different structures generated due to rotation about C-C axis are called conformers, and this phenomenon is called conformational isomerism.
306
Hard
306 of 392
Analyzing
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Arrange the following in decreasing order of acidic strength.
(i) Benzoic acid
(ii) 4-nitrobenzoic acid
(iii) 3,4-dinitrobenzoic acid
(iv) 4-methoxy benzoic acid
(i) Benzoic acid
(ii) 4-nitrobenzoic acid
(iii) 3,4-dinitrobenzoic acid
(iv) 4-methoxy benzoic acid
View answer and explanation
Correct option: A
III II I IV
Option A (III II I IV) is correct because electron-withdrawing groups increase acidity, while electron-donating groups decrease acidity.
307
Hard
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Application
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The silver salt of a monobasic acid on ignition gave 60% of Ag. The molecular weight of the acid is
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Correct option: C
73
Option C (73) is correct because the molecular weight of the acid can be determined from the percentage of silver in the silver salt.
308
Easy
308 of 392
Analyzing
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Which of the following is strongest nucleophile
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Correct option: C
Option C () is the strongest nucleophile because carbon is less electronegative than oxygen, making the carbon atom in cyanide more willing to donate its electrons compared to the oxygen in hydroxide or ethoxide. Also, cyanide is a weaker base than ethoxide, making it a better nucleophile.
309
Easy
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Understanding
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The correct IUPAC name of is
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Correct option: A
3-Chloroprop-1-ene
Option A (3-Chloroprop-1-ene) is correct because the chlorine is on the 3rd carbon and the double bond starts at the 1st carbon.
310
Medium
310 of 392
Application
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If a compound on analysis was found to contain and then its empirical formula is
View answer and explanation
Correct option: D
Option D () is correct because the mole ratio of C:H:Cl:O is approximately 1:1:1:1, which corresponds to the empirical formula .
311
Medium
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Application
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The number of optical isomers of 2, 3-dihydroxy butanal is
View answer and explanation
Correct option: B
4
Option B (4) is correct because 2,3-dihydroxybutanal has two chiral centers, and since it's not a meso compound, the number of stereoisomers is 2^n = 22 = 4.
312
Hard
312 of 392
Understanding
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Given below are two statements:
Statement I: Emulsions of oil in water are unstable and sometimes they separate into two layers on standing.
Statement II: For stabilisation of an emulsion, excess of electrolyte is added.
In the light of the above statements, choose the most appropriate answer from the options given below:
Statement I: Emulsions of oil in water are unstable and sometimes they separate into two layers on standing.
Statement II: For stabilisation of an emulsion, excess of electrolyte is added.
In the light of the above statements, choose the most appropriate answer from the options given below:
View answer and explanation
Correct option: C
Statement I is correct but Statement II is incorrect.
Option C is correct because emulsions are indeed unstable, but adding excess electrolyte destabilizes them further, not stabilizes them.
313
Easy
313 of 392
Analyzing
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In what order the reagents and are added to an aqueous solution containing and ions in order to precipitate first, second and last.
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Correct option: D
Option D () is correct because the solubility products () of the silver, copper, and nickel salts determine the order of precipitation.
314
Medium
314 of 392
Understanding
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A strong base can abstract an α-hydrogen from :
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Correct option: B
Ketone
Option B (Ketone) is correct because ketones have alpha hydrogens that are relatively acidic due to the adjacent carbonyl group, making them susceptible to abstraction by a strong base.
315
Easy
315 of 392
Understanding
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Which of the following is a primary halide?
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Correct option: D
Neo hexyl chloride
Option D (Neo hexyl chloride) is correct because the chlorine atom is attached to a primary carbon (a carbon bonded to only one other carbon).
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316
Medium
316 of 392
Analyzing
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Among the following the most stable compound is:
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Correct option: D
trans-1,3-cyclohexanediol
Option D is correct because trans-1,3-cyclohexanediol is the most stable due to the hydroxyl groups being in equatorial positions, minimizing steric hindrance.
317
Medium
317 of 392
Remembering
+4 | -1
The weakest +M group of the given species is:
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Correct option: C
Option C () is correct because Iodine is the least electron-donating group among the given options due to its lower electronegativity compared to the others.
318
Medium
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Understanding
+4 | -1
Rotational angle requires to get maximum stable conformer from minimum stable conformer in -butane is
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Correct option: B
Option B () is correct because the most stable conformer (anti) and the least stable conformer (eclipsed) in n-butane are 180 degrees apart in terms of rotational angle.
319
Medium
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Remembering
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The permanent displacement of electron through a chain involving only -bonds is called
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Correct option: A
inductive effect
Option A (inductive effect) is correct because the permanent displacement of electrons through a chain involving only sigma bonds is the definition of the inductive effect.
320
Medium
320 of 392
Analyzing
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Which of the following organic compounds has same hybridization as its combustion product
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Correct option: B
Ethyne
Option B (Ethyne) is correct because ethyne (C₂H₂) has sp hybridization, and its combustion product, CO₂, also has sp hybridization.
321
Medium
321 of 392
Analyzing
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In which of the following electrons of the halogens are not involved in delocalisation?
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Correct option: C
Allyl chloride
Option C (Allyl chloride) is correct because the p-electrons of the halogen are not directly conjugated with the pi system of the double bond. The chlorine is attached to an sp3 carbon adjacent to the double bond.
322
Easy
322 of 392
Remembering
+4 | -1
Carbon and hydrogen are estimated in organic compounds by
View answer and explanation
Correct option: C
Leibig's method
Option C (Leibig's method) is correct because Leibig's method is used for the estimation of carbon and hydrogen in organic compounds.
323
Medium
323 of 392
Application
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Which one of the following will show optical isomerism?
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Correct option: B
Option B (H3C - CH(OH) - CO2H) is correct because the central carbon atom is bonded to four different groups (H, CH3, OH, and CO2H), making it a chiral center.
324
Hard
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Understanding
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Arrange the following in order of reactivity towards sulphonation with fuming sulphuric acid
a) Benzene b) Toluene c) Methoxy benzene d) Chloro benzene
a) Benzene b) Toluene c) Methoxy benzene d) Chloro benzene
View answer and explanation
Correct option: B
c > b > a > d
Option B (c > b > a > d) is correct because methoxybenzene (c) is the most activating group due to the +M effect of -OCH3, followed by toluene (b) with a +I effect of -CH3, then benzene (a), and finally chlorobenzene (d) which is deactivating due to the -I effect of -Cl.
325
Easy
325 of 392
Understanding
+4 | -1
In the hydrocarbon . the state of hybridisation of 1, 3 and 5 are in the following sequence
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Correct option: B
Option B () is correct because carbon 1 is sp hybridized, carbon 3 is sp3 hybridized, and carbon 5 is sp2 hybridized.
326
Easy
326 of 392
Application
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Which of the following molecules represents the order of hybridization from left to right atoms
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Correct option: B
Option B () is correct because the hybridization of the carbon atoms from left to right is SP2, SP2, SP, SP.
327
Hard
327 of 392
Analyzing
+4 | -1
Correct order of acidity is as follows
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Correct option: D
Option D () is correct because the acidity order is based on the stability of the conjugate base and the strength of the acid.
328
Medium
328 of 392
Analyzing
+4 | -1
How many isomers of will be primary alcohols?
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Correct option: B
4
Option A (4) is correct because there are four isomers of that are primary alcohols.
329
Easy
329 of 392
Understanding
+4 | -1
Overlap of which of the following atomic orbitals would be maximum to form the strongest covalent bond?
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Correct option: B
Option B (1s - 2p(σ)) is correct because sigma bonds formed by the overlap of s and p orbitals are generally stronger than those formed by s-s overlap, and much stronger than pi bonds from p-p overlap.
330
Medium
330 of 392
Remembering
+4 | -1
Which is most commonly used to dry organic liquids?
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Correct option: B
Sodium
The correct answer is Sodium because it reacts with water present in the organic liquid to form hydrogen gas and sodium hydroxide, effectively drying the liquid.
Revision notes and key takeaways
Review ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES in your textbook or class notes, then use this set to check your understanding.
Showing 301-330 of 392 questions
