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JEE • CHEMISTRY • SOLUTIONS

Solutions practice · Medium

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Showing 181-210 of 265 questions

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181 Medium
181 of 265
Application +4 | -1
Van't Hoff factor for the aqueous solution of AlCl3\mathrm{AlCl}_3 is 2.8. The percentage dissociation of AlCl3\mathrm{AlCl}_3 is:
View answer and explanation
Correct option: A
60%60 \%
Option A (60%60 \%) is correct because it calculates the percentage dissociation using the Van't Hoff factor and the number of ions produced.
182 Medium
182 of 265
Application +4 | -1
Which of the following solutions boils at the highest temperature
View answer and explanation
Correct option: B
0.1 M NaCl0.1 \,{M} \,{NaCl}
Option B (0.1 M NaCl0.1 \,{M} \,{NaCl}) is correct because NaCl dissociates into two ions, resulting in a higher effective concentration of particles and thus a greater elevation in boiling point compared to the other options.
183 Medium
183 of 265
Analyzing +4 | -1
Which of the following on addition in 1.0 molal KI solution will give rise to increase a vapour pressure?
View answer and explanation
Correct option: D
addition of water
Option D (addition of water) is correct because adding water dilutes the solution, increasing the surface area available for solvent evaporation and thus increasing the vapor pressure.
184 Medium
184 of 265
Application +4 | -1
11.2 L11.2 \mathrm{~L} of HCl(g){HCl}({g}) is completely dissolved in 500 ml500 \mathrm{~ml} of aqueous solution. The molality of the solution is
View answer and explanation
Correct option: C
1 m1 \mathrm{~m}
Option C (1 m1 \mathrm{~m}) is correct because the molality is calculated by dividing the number of moles of HCl by the volume of the solution in liters.
185 Medium
185 of 265
Application +4 | -1
What is the molality of pure water?
View answer and explanation
Correct option: C
55.5
Option C (55.5) is correct because the molality of pure water is calculated by dividing 1000 g/kg by the molar mass of water.
186 Medium
186 of 265
Application +4 | -1
In an osmotic pressure measurement experiment, a 5%5\% solution of compound ‘X’ is found to be isotonic with a 2%2\% acetic acid solution . The gram molecular mass of ‘X’ is
View answer and explanation
Correct option: C
150
Option C (150) is correct because the gram molecular mass of X is calculated by equating the molarities of the isotonic solutions and using the given percentages.
187 Medium
187 of 265
Application +4 | -1
The temperature at which 10%10 \% aqueous solution (w/V)(w / V) of glucose exhibits the osmotic pressure of 16.4 atm16.4 \mathrm{~atm}, is (R=0.082 dm3 atm K Kol−1)\left(R=0.082 \mathrm{~dm}^3 \mathrm{~atm} \mathrm{~K} \mathrm{~Kol}^{-1}\right)
View answer and explanation
Correct option: D
360 K360 \mathrm{~K}
Option D (360 K360 \mathrm{~K}) is correct because it is calculated using the osmotic pressure formula and the given values for concentration, osmotic pressure, and the gas constant.
188 Medium
188 of 265
Understanding +4 | -1
Statement I: Reverse osmosis is used in the desali- nation of sea water.

Statement II: When the applied pressure is more than the osmotic pressure, pure water is squeezed out of sea water through the membrane.
View answer and explanation
Correct option: A
If both Statement I and Statement II are correct and Statement II is the correct explanation of Statement I
Option A is correct. Reverse osmosis uses pressure greater than osmotic pressure to force pure water through a semipermeable membrane, effectively desalinating seawater.
189 Medium
189 of 265
Analyzing +4 | -1
Statement - I: When an ideal binary solution of liquids A and B is distilled, the boiling point of
the distillate becomes lower than that of the parental liquid solution.

Statement - II: When an ideal binary solution of liquids A and B is distilled, the distillate
contains relatively larger amount of the more volatile liquid.
View answer and explanation
Correct option: A
If both Statement-I and Statement-II are true, and Statement-II is the correct
explanation of Statement-I
Option A is correct because when an ideal binary solution is distilled, the distillate has a lower boiling point and contains more of the volatile liquid.
190 Medium
190 of 265
Application +4 | -1
The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is 0.0125. The molality of the solution is
View answer and explanation
Correct option: A
0.700.70
The correct answer is A (0.70) because it correctly uses Raoult's law and the relationship between relative lowering of vapor pressure and molality.
191 Medium
191 of 265
Understanding +4 | -1
If molality of the dilute solutions is doubled, the value of molal depression constant (Kf)\left({K}_{{f}}\right) will be
View answer and explanation
Correct option: C
Unchanged
The correct answer is C (Unchanged) because the molal depression constant (Kf) is a property of the solvent and is independent of the solute's molality.
192 Medium
192 of 265
Application +4 | -1
A liquid solution is formed by mixing 10 moles of aniline and 20 moles of phenol at a temperature where the vapour pressures of pure liquid aniline and phenol are 9090 and 87 mm Hg,87 \mathrm{~mm} \mathrm{~Hg}, respectively. The possible vapour pressure of solution at that temperature is
View answer and explanation
Correct option: A
82 mm Hg82 \mathrm{~mm} \mathrm{~Hg}
Option A (82 mm Hg82 \mathrm{~mm} \mathrm{~Hg}) is correct because the solution exhibits negative deviation from Raoult's law, resulting in a vapor pressure lower than the ideal value.
193 Medium
193 of 265
Application +4 | -1
Two liquids AA and BB are mixed in a ratio of 2:32: 3. If PA∘=100 mmHgP_A^{\circ}=100 \,{mmHg} and PB∘=300 mmHgP_B^{\circ}=300 \,{mmHg}, then the mole fraction of AA in vapour phase will be
View answer and explanation
Correct option: A
211\frac{2}{11}
Option A (2/11) is correct because it is calculated by first finding the partial pressures of A and B and then using those to calculate the mole fraction of A in the vapor phase.
194 Medium
194 of 265
Analyzing +4 | -1
The boiling point of 0.2 mol kg−10.2 \mathrm{~mol} \mathrm{~kg}^{-1} solution X{X} in water is greater than equimolal solution of Y{Y} in water. Which one of the following statements is true in this case?
View answer and explanation
Correct option: D
XX is undergoing dissociation is water
Option D (XX is undergoing dissociation is water) is correct because a higher boiling point elevation for XX indicates a larger van't Hoff factor, implying dissociation.
195 Medium
195 of 265
Application +4 | -1
Two liquids X and Y form an ideal solution at 300K,vapour pressure of the solution containing 1 mol of X and 3, mol of Y is 550 mmHg. At the same temperature, if 1 mol of Y is further added to this solution, vapour pressure of the solution increases by 10 mmHg. Vapour pressure (in mmHg)of XandY in their pure states will be, respectively
View answer and explanation
Correct option: C
400 and 600
Option C (400 and 600) is correct because the vapor pressures of X and Y are calculated using Raoult's law and solving the system of equations.
196 Medium
196 of 265
Understanding +4 | -1
Assertion: Soda bottles are sealed under high pressure.

Reason: High pressure increases the solubility of carbon dioxide gas.
View answer and explanation
Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
Option A (Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.) is correct because high pressure increases the solubility of gases in liquids, which is why soda bottles are sealed under high pressure to keep the carbon dioxide dissolved.
197 Medium
197 of 265
Understanding +4 | -1
The value of Henry's constant KHK_{\mathrm{H}} is
View answer and explanation
Correct option: B
greater for gases with lower solubility.
Option B (greater for gases with lower solubility) is correct because Henry's law states that the partial pressure of a gas is directly proportional to its solubility, with Henry's constant being the proportionality constant. Therefore, higher Henry's constant implies lower solubility.
198 Medium
198 of 265
Application +4 | -1
At 300 K300 \mathrm{~K}, the vapour pressure of an ideal solution containing 1 mole of liquid A{A} and 2 moles of liquid B{B} is 500 mm500 \mathrm{~mm} of Hg\mathrm{Hg}. The vapour pressure of the solution increases by 25 mm25 \mathrm{~mm} of Hg\mathrm{Hg} if one more mole of B{B} is added to the above ideal solution at 300 K300 \mathrm{~K}. The vapour pressure of AA in pure state is (in mm\mathrm{mm} of Hg\mathrm{Hg} ) :-
View answer and explanation
Correct option: A
300
Option A (300) is correct because it is derived from Raoult's Law by setting up and solving a system of equations based on the given vapor pressures.
199 Medium
199 of 265
Analyzing +4 | -1
Assertion: On mixing aniline and Acetone shows +ve deviation.

Reason: Interaction between Acetone and aniline is weaker than interaction of AcetoneAcetone and aniline-aniline.
View answer and explanation
Correct option: D
If both Assertion & Reason are false
Option D is correct because both the Assertion and the Reason are false. Aniline and acetone show negative deviation, and the interaction between them is stronger.
200 Medium
200 of 265
Application +4 | -1
Mole fraction of solute in an aqueous solution which boils at 100.104. Kb  for  H2O=0.52  K  molality−1{K_b}\;for\;{\mathrm{H}_2}\mathrm{O} = 0.52\;K\;\mathrm{molalit}{\mathrm{y}^{ - 1}}:
View answer and explanation
Correct option: B
0.0040.004
Option B (0.004) is correct because it calculates the mole fraction of the solute using the elevation in boiling point and the ebullioscopic constant.
201 Medium
201 of 265
Understanding +4 | -1
Assertion: At high altitude cooking food is difficult.

Reason: Water boils at high temperature.
View answer and explanation
Correct option: C
If Assertion is True but the Reason is False
Option D (9.32 eV, 8.29 eV) is correct because Beryllium (Be) has a higher ionization potential than Boron (B) due to its stable, fully-filled 2s orbital configuration.
202 Medium
202 of 265
Application +4 | -1
How many grams of cane sugar are present in 534.2 g534.2 \mathrm{~g} of its aqueous solution having molality 0.2?
View answer and explanation
Correct option: B
34.2
Option B (34.2) is correct because it is the mass of cane sugar calculated using the given molality and the mass of the solution.
203 Medium
203 of 265
Analyzing +4 | -1
For each of the following dilute solutions, van't Hoff factor is equal of 3, except:
View answer and explanation
Correct option: C
K3PO4\mathrm{K}_3 \mathrm{PO}_4
Option C (K3PO4\mathrm{K}_3 \mathrm{PO}_4) is correct because it dissociates into 4 ions, resulting in a van't Hoff factor of 4.
204 Medium
204 of 265
Analyzing +4 | -1
A liquid freezes at 7∘C7^{\circ} \mathrm{C} and boils at 77∘C.77^{\circ} \mathrm{C}. If the KfK_{\mathrm{f}} and KbK_{\mathrm{b}} values for the liquid are 5.65.6 and 2.5 deg/molal,2.5 \, \mathrm{deg} / \mathrm{molal}, respectively, then the ratio of molar latent heat of fusion to molar latent heat of vaporization is
View answer and explanation
Correct option: C
2:72: 7
The correct answer is C (2:7) because it is calculated using the ratio of Kf/Kb and the squares of the freezing and boiling points.
205 Medium
205 of 265
Remembering +4 | -1
The pressure under which liquid and its vapour can coexist in equilibrium is known as:
View answer and explanation
Correct option: B
Saturated vapour pressure
Option B (Saturated vapour pressure) is correct because it is the pressure exerted by a vapor in equilibrium with its liquid at a given temperature.
206 Medium
206 of 265
Application +4 | -1
In an osmotic pressure measurement experiment, a 5%5\% solution of compound ‘X’ is found to be isotonic with a 2%2\% acetic acid solution . The gram molecular mass of ‘X’ is
View answer and explanation
Correct option: C
150
Option C (150) is correct because the gram molecular mass of X is calculated by equating the molarities of the isotonic solutions and using the given percentages.
207 Medium
207 of 265
Understanding +4 | -1
The Van't Hoff factor will be highest for
View answer and explanation
Correct option: C
Sodium phosphate
Option C (Sodium phosphate) is correct because it dissociates into the highest number of ions (4), leading to the highest van't Hoff factor.
208 Medium
208 of 265
Understanding +4 | -1
For a binary ideal liquid solution, the total pressure of the solution is given as:
View answer and explanation
Correct option: B
Ptotal =PB∘+(PA∘−PB∘)XAP_{\text {total }}=P_B^{\circ}+\left(P_A^{\circ}-P_B^{\circ}\right) X_A
Option B (Ptotal =PB∘+(PA∘−PB∘)XAP_{\text {total }} = P_B^{\circ} + (P_A^{\circ} - P_B^{\circ}) X_A) is correct because it represents Raoult's law for an ideal binary solution, expressing total pressure in terms of mole fraction and vapor pressures of pure components.
209 Medium
209 of 265
Analyzing +4 | -1
Assertion: Van't Hoff factor is always more or equal to one.

Reason: Van't Hoff factor is the ratio of experimental colligative properties to observed colligative properties.
View answer and explanation
Correct option: D
If both Assertion & Reason are false
The correct answer is D (If both Assertion & Reason are false) because the Van't Hoff factor can be less than 1 for association, and the Reason incorrectly defines the Van't Hoff factor as the inverse ratio.
210 Medium
210 of 265
Application +4 | -1
A 5% solution of cane sugar (Molar mass 342) is isotonic with 1% of a solution of an unknown solute. The molar mass of unknown solute is
View answer and explanation
Correct option: C
68.468.4
Option C (Mol. wt./6) is correct because the equivalent weight is calculated by dividing the molecular weight by the change in oxidation number of iodine in the reaction.
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