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JEE • CHEMISTRY • ELECTRO CHEMISTRY

Electro chemistry practice · Hard

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These sets use single-correct-answer MCQs. They do not cover every JEE Main or JEE Advanced question format and are not full-length mock papers.

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61 Hard
61 of 63
Application +4 | -1
The resistance of 0.5 NN solution of an electrolyte in a conductivity cell was found to be 45 ohms. The equivalent conductivity of the same solution is …..if the electrodes in the cell are 2.2 cm apart and have an area of 3.8 cm2\mathrm{c}{\mathrm{m}^2}.
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Correct option: A
25.73
Option A (25.73) is correct because it is calculated using the formula for equivalent conductivity, considering the cell constant and resistance.
62 Hard
62 of 63
Application +4 | -1
Using the SRP values given below, decide which of the statements I, II, III and IV are correct.
Fe2++2e−⇋Fe ; Eo=−0.44 VCu+2+2e−⇋Cu ; Eo=+0.34 VAg++e−⇋Ag ; Eo=+0.80 V\begin{array}{l} F{e^{2 + }} + 2{e^ - }\underset{{}}{\overset{{}}{\leftrightharpoons}}Fe\,;\,{E^\mathrm{o}} = - 0.44\,V\\ C{u^{ + 2}} + 2{e^ - }\underset{{}}{\overset{{}}{\leftrightharpoons}}Cu\,;\,{E^\mathrm{o}} = + 0.34\,V\\ A{g^ + } + {e^ - }\underset{{}}{\overset{{}}{\leftrightharpoons}}Ag\,;\,{E^\mathrm{o}} = + 0.80\,V \end{array}
(I) Copper can displace iron from FeSO4FeS{O_4} solution
(II) Iron can displace copper from CuSO4CuS{O_4} solution
(III) Silver can displace copper from CuSO4CuS{O_4} solution
(IV) Iron can displace silver from AgNO3AgN{O_3} solution
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Correct option: C
II and IV
Option C (II and IV) is correct because iron can displace copper from copper sulfate solution and iron can displace silver from silver nitrate solution due to their relative SRP values.
63 Hard
63 of 63
Application +4 | -1
When electric current is passed through acidified water for 1930 s, 1120mL of H2{\mathrm{H}_2} gas is collected (at STP) at the cathode. What is the current passed in amperes?
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Correct option: C
5
Option C (5) is correct because the current passed is calculated using Faraday's laws of electrolysis, relating the amount of hydrogen gas collected to the charge passed through the solution.
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