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JEE CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Two electrolytic cells one containing acidified ferrous chloride and another acidified ferric chloride are connected in series. The ratio of iron deposited at cathodes in the two cells when electricity is passed through the cells will be
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Correct option: D
0.126388889
Option D (03:02) is correct because the ratio of iron deposited is determined by the ratio of their equivalent weights.

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At 25∘C25^{\circ} \mathrm{C}, the standard emf of cell having reactions involving two electron change is found to be 0.295 V0.295 \mathrm{~V}. The equilibrium constant of the reaction is Which are used as secondary reference electrodes? For the following cell with hydrogen electrodes at two different pressures p1andp2{p_1}{\kern 1pt} {\kern 1pt} \mathrm{and}{\kern 1pt} {\kern 1pt} {p_2}

Pt(H2)p1∣H+(aq)1M∣Pt(H2)p2\mathop {\mathrm{Pt}\left( {{\mathrm{H}_2}} \right)}\limits_{{p_1}} \left| {\mathop {{\mathrm{H}^ + }\left( {aq} \right)}\limits_{1\mathrm{ }M} } \right|\mathop {Pt\left( {{\mathrm{H}_2}} \right)}\limits_{{p_2}}

emf is given by
A current of strength 2.5 A was passed through CuSO4\mathrm{CuS}{\mathrm{O}_4} solution for 6 min 26 s. The amount of copper deposited is (At. Wt. of Cu = 63.5, 1F = 96500 C) A current strength of 9.65 amperes is passed through excess fused AlCl3{AlCl}_3 for 5 hours. How many litres of chlorine will be liberated at STPSTP? (F=96500C)({F}=96500 {C}) The electrode potential (in millivolts) of 2Ag(s)+S2−(aq)→Ag2S(s)+2e−2 \mathrm{Ag}(\mathrm{s})+\mathrm{S}^{2-}(\mathrm{aq}) \rightarrow \mathrm{Ag}_2 \mathrm{S}(\mathrm{s})+2 \mathrm{e}^{-} in a solution buffered at pH=3\mathrm{pH}=3 and which is also saturated with 0.1 M−H2S,0.1 \mathrm{~M}-\mathrm{H}_2 \mathrm{S}, is (Given: for H2S,Ka1=10−8;Ka2=10−13,Ksp\mathrm{H}_2 \mathrm{S}, K_{\mathrm{a}_1}=10^{-8} ; K_{\mathrm{a}_2}=10^{-13}, K_{\mathrm{sp}} of Ag2S=4×10−48,\mathrm{Ag}_2 \mathrm{S}=4 \times 10^{-48}, EAg∣Ag+∘=0.80 V,E^{\circ}_{{\mathrm{Ag} | \mathrm{Ag}}^{+}}=0.80 \mathrm{~V}, log⁡2=0.3,\log 2=0.3, 2.303RT/F=0.062.303 R T / F=0.06)
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