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NEET • CHEMISTRY • SURFACE CHEMISTRY

Surface chemistry practice · Mixed difficulty

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Showing 121-139 of 139 questions

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121 Medium
121 of 139
Understanding +4 | -1
If xx is amount of adsorbate and mm is amount of adsorbent, which of the following relations is related to adsorption process?
View answer and explanation
Correct option: A
xm=P×T\frac{x}{m} = P \times T
Option B (xm=f(P)\frac{x}{m} = f\left( P \right) at constant T) is correct because it represents the relationship between the amount of adsorbate adsorbed per unit mass of adsorbent as a function of pressure at a constant temperature, which is the basis of adsorption isotherms.
122 Easy
122 of 139
Remembering +4 | -1
Which adsorption takes place at low temperature?
View answer and explanation
Correct option: A
Physical
Option A is correct because physical adsorption (physisorption) is favored at low temperatures due to weak van der Waals forces.
123 Easy
123 of 139
Application +4 | -1
Which of the following is the most effective in the coagulation of gold sol?
View answer and explanation
Correct option: B
MgCl2\mathrm{MgC}{\mathrm{l}_2}
Option B (MgCl2\mathrm{MgC}{\mathrm{l}_2}) is correct because gold sol is negatively charged, and according to the Hardy-Schulze rule, the cation with the highest charge will be most effective for coagulation. Mg2+Mg^{2+} has a higher charge than Na+Na^+.
124 Easy
124 of 139
Remembering +4 | -1
Which of the following statements is correct about Langmuir’s adsorption isotherm?
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Correct option: A
It forms monolayer
Option A (It forms monolayer) is correct because Langmuir's adsorption isotherm assumes the formation of a monolayer of adsorbate on the adsorbent surface.
125 Medium
125 of 139
Remembering +4 | -1
The heat evolved in physisorption lies in the range (kJ/mol) of
View answer and explanation
Correct option: A
20-40
Option A (20-40) is correct because the heat evolved in physisorption is generally in the range of 20-40 kJ/mol due to weak van der Waals forces.
126 Medium
126 of 139
Understanding +4 | -1
The coagulating power of ions for haemoglobin decreases in the order
View answer and explanation
Correct option: B
PO43−>SO42−>Cl−PO_4^{3 - } > SO_4^{2 - } > C{l^ - }
Option D (PO43−>SO42−>Cl−PO_4^{3 - } > SO_4^{2 - } > C{l^ - }) is correct because the coagulating power increases with the charge of the ion, according to the Hardy-Schulze rule.
127 Easy
127 of 139
Analyzing +4 | -1
Flocculation value of BaCl2\mathrm{BaCl}_2 is much less than that of KCl\mathrm{KCl} for sol A\mathrm{A} and flocculation value of Na2SO4\mathrm{Na}_2 \mathrm{SO}_4 is much less than that of NaBr\mathrm{NaBr} for sol B\mathrm{B}. The correct statement among the following is
View answer and explanation
Correct option: B
Sol A is positively charged and Sol B is negatively charged.
Option B is correct because the flocculation value is inversely proportional to the charge on the sol. Lower flocculation value implies higher charge, hence A is positive and B is negative.
128 Easy
128 of 139
Remembering +4 | -1
In physical adsorption gas molecules are bound on the solid surface by
View answer and explanation
Correct option: D
Van der Waals’ forces
Option D (Van der Waals’ forces) is correct because physical adsorption involves weak intermolecular forces, specifically Van der Waals forces, between the gas molecules and the solid surface.
129 Hard
129 of 139
Application +4 | -1
One gram of activated carbon has a surface area of 1000 m21000 \mathrm{~m}^2. Considering complete coverage as well as monomolecular adsorption, how much ammonia at 1 atm1 \mathrm{~atm} and 273 K273 \mathrm{~K} would be adsorbed on the surface of 447 g\frac{44}{7} \mathrm{~g} carbon if radius of a ammonia molecules is 10−8 cm10^{-8} \mathrm{~cm}.
View answer and explanation
Correct option: A
7.46
Option A (7.46) is correct because it is the calculated amount of ammonia adsorbed based on the given surface area and molecular radius.
130 Medium
130 of 139
Application +4 | -1
The graph of log⁡xm\log \frac{x}{m} vs log⁡p\log p for an adsorption process is a straight line inclined at an angle of 45∘45^{\circ} with intercept equal to 0.6020 . The mass of gas adsorbed per unit mass of adsorbent at the pressure of _____ 0.4 atm0.4 \mathrm{~atm} is ×10−1\times 10^{-1} (Nearest integer).

Given : log⁡2=0.3010\log 2=0.3010
View answer and explanation
Correct option: A
16
Option A (16) is correct because the mass of gas adsorbed per unit mass of adsorbent is calculated using the Freundlich isotherm, resulting in 1.6, which is 16 × 10-1.
131 Easy
131 of 139
Analyzing +4 | -1
Select wrong statement.
View answer and explanation
Correct option: A
If a very small amount of AlCl3\mathrm{AlC}{\mathrm{l}_3} is added to gold sol, coagulation occurs, but if a large quantity of AlCl3\mathrm{AlC}{\mathrm{l}_3} is added, there is no coagulation.
Option A is the wrong statement because adding a large quantity of electrolyte to a sol can lead to peptization, not necessarily preventing coagulation.
132 Medium
132 of 139
Remembering +4 | -1
Which of the following is an example of associated colloid
View answer and explanation
Correct option: A
Soap in water
Option A (Soap in water) is correct because soap molecules in water aggregate to form micelles, which are characteristic of associated colloids.
133 Easy
133 of 139
Application +4 | -1
Which of the following will be the most effective in the coagulation of Fe(OH)3\mathrm{Fe}{\left( {\mathrm{OH}} \right)_3} sol?
View answer and explanation
Correct option: D
Mg3(PO4)2\mathrm{M}{\mathrm{g}_3}{\left( {\mathrm{P}{\mathrm{O}_4}} \right)_2}
Option D (Mg3(PO4)2\mathrm{M}{\mathrm{g}_3}{\left( {\mathrm{P}{\mathrm{O}_4}} \right)_2}) is correct because, according to the Hardy-Schulze rule, the ion with the highest charge will have the maximum coagulation power. Since Fe(OH)3\mathrm{Fe}{\left( {\mathrm{OH}} \right)_3} is a positive sol, we need to look for the anion with the highest charge, which is PO43−PO_4^{3-}.
134 Easy
134 of 139
Remembering +4 | -1
The process which is catalysed by one of the products formed during the reaction is known as :
View answer and explanation
Correct option: A
Autocatalysis
The correct answer is A (Autocatalysis) because autocatalysis is when a product of the reaction acts as a catalyst.
135 Easy
135 of 139
Remembering +4 | -1
The enzyme which converts starch to maltose is
View answer and explanation
Correct option: A
Diastase
Option A is correct because diastase is the enzyme that specifically catalyzes the hydrolysis of starch into maltose.
136 Medium
136 of 139
Understanding +4 | -1
Mention the type of reaction to obtain Au(sol)\mathrm{Au}\left( {\mathrm{sol}} \right).
Reaction,

2AuCl3+3HCHO+3H2O→2Au(sol)+3HCOOH+6HCl2\mathrm{AuC}{\mathrm{l}_3} + 3\mathrm{HCHO} + 3{\mathrm{H}_2}\mathrm{O} \to 2\mathrm{Au}\left( {\mathrm{sol}} \right) + 3\mathrm{HCOOH} + 6\mathrm{HCl}
View answer and explanation
Correct option: C
Reduction
Option C (Reduction) is correct because the gold ions (AuCl3\mathrm{AuC}{\mathrm{l}_3}) are reduced to gold atoms (Au\mathrm{Au}) in the reaction.
137 Easy
137 of 139
Remembering +4 | -1
The critical micelle concentration (CMC) is
View answer and explanation
Correct option: A
The concentration at which micellisation starts
Option A (The concentration at which micellisation starts) is correct because CMC is defined as the minimum concentration at which micelles begin to form.
138 Easy
138 of 139
Understanding +4 | -1
Which is not correct for catalyst? It :
View answer and explanation
Correct option: B
Changes enthalpy of reaction
Option B (Changes enthalpy of reaction) is correct because a catalyst does not change the enthalpy of the reaction; it only affects the rate.
139 Medium
139 of 139
Analyzing +4 | -1
Assertion : In chemisorption, adsorption first increases with temperature and then decreases.

Reason : Heat keeps on providing more and more activation energy.
View answer and explanation
Correct option: C
If Assertion is correct but Reason is incorrect.
The correct answer is 'If Assertion is correct but Reason is incorrect' because chemisorption initially increases with temperature, but the reason is incorrect as heat eventually decreases adsorption.
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