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NEET • CHEMISTRY • P-BLOCK ELEMENTS

P-block elements practice · Medium

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Showing 31-60 of 93 questions
31 Medium
31 of 93
Application +4 | -1
SbF5{SbF}_5 reacts with XeF4{XeF}_4 and XeF6{XeF}_6 to form ionic compounds [XeF3+][SbF6]−\left[{XeF}_3^{+}\right]\left[{SbF}_6\right]^{-} and [XeF5+][SbF6−].\left[{XeF}_5^{+}\right]\left[{SbF}_6^{-}\right]. The geometry of XeF3+{XeF}_3{ }^{+} ion and XeF5+{XeF}_5{ }^{+} ion, respectively, is:
View answer and explanation
Correct option: B
Bent T-shaped, square pyramidal
Option B (Bent T-shaped, square pyramidal) is correct because the geometries of XeF3+\mathrm{XeF}_3^+ and XeF5+\mathrm{XeF}_5^+ are bent T-shaped and square pyramidal, respectively, based on VSEPR theory.
32 Medium
32 of 93
Understanding +4 | -1
At ordinary temperature and pressure, among halogens, the chlorine is a gas, bromine is a liquid and iodine is a solid. This is because:
View answer and explanation
Correct option: A
The specific heat is in the order Cl2>Br2>I2\mathrm{C}{\mathrm{l}_2} > B{\mathrm{r}_2} > {\mathrm{I}_2}
Option B (Intermolecular forces among molecules of chlorine are the weakest and those in iodine are the strongest) is correct because the physical state of halogens at room temperature depends on the strength of intermolecular forces, which increase with molecular size.
33 Medium
33 of 93
Remembering +4 | -1
The substance used in Holme’s signal of the ship is a mixture of
View answer and explanation
Correct option: A
CaC2+Ca3P2\mathrm{Ca}{\mathrm{C}_2} + \mathrm{C}{\mathrm{a}_3}{\mathrm{P}_2}
Option A (CaC2+Ca3P2\mathrm{Ca}{\mathrm{C}_2} + \mathrm{C}{\mathrm{a}_3}{\mathrm{P}_2}) is correct because the mixture of calcium carbide and calcium phosphide produces acetylene and phosphine, which ignite spontaneously and produce a bright light, used as a signal on ships.
34 Medium
34 of 93
Application +4 | -1
H2SO4  and  H2SO3{\mathrm{H}_2}\mathrm{S}{\mathrm{O}_4}\mathrm{\;and\;}{\mathrm{H}_2}\mathrm{S}{\mathrm{O}_3} can be distinguished by the addition of:
View answer and explanation
Correct option: B
FeCl3  solution\mathrm{FeC}{\mathrm{l}_3}\mathrm{\;solution}
Option B (FeCl3  solution\mathrm{FeC}{\mathrm{l}_3}\mathrm{\;solution}) is correct because FeCl3FeCl_3 can oxidize H2SO3H_2SO_3 to H2SO4H_2SO_4, while H2SO4H_2SO_4 cannot reduce Fe3+Fe^{3+} to Fe2+Fe^{2+}.
35 Medium
35 of 93
Understanding +4 | -1
Stability of hydrides generally increases with:
View answer and explanation
Correct option: A
Increase in bond angle
Option A (Increase in bond angle) is correct because as the bond angle increases, the s-character in the bonding orbitals increases, leading to greater stability.
36 Medium
36 of 93
Analyzing +4 | -1
A salt X gives white precipitates with lead acetate solution, insoluble in hot water and nitric acid. The salt X most probably contains:
View answer and explanation
Correct option: C
SO42−SO_4^{2 - }
Option C (SO42−SO_4^{2 - }) is correct because lead sulfate (PbSO4PbSO_4) is a white precipitate insoluble in hot water and nitric acid.
37 Medium
37 of 93
Application +4 | -1
The oxidation states of P{P} in the following compounds H3PO3,PCl3,Ca3P2,Na3PO4,POF3{H}_3 {PO}_3, {PCl}_3, {Ca}_3 {P}_2, {Na}_3 {PO}_4, {POF}_3 are respectively be
View answer and explanation
Correct option: A
+3,+3,−3,+5,+5+3, +3, -3, +5, +5
Option A (+3, +3, -3, +5, +5) is correct because it accurately represents the oxidation states of P in each compound, calculated based on electronegativity differences and charge neutrality.
38 Medium
38 of 93
Analyzing +4 | -1
Which of the following reaction gives a gas which act as oxidising agent as well as reducing agent :
View answer and explanation
Correct option: A
Na2SO3+HClN{a_2}S{O_3} + HCl
Option A (Na2SO3+HClN{a_2}S{O_3} + HCl) is correct because the reaction produces SO2SO_2, which can act as both an oxidizing and reducing agent.
39 Medium
39 of 93
Application +4 | -1
Iron sulphide is heated in air to form A. an oxide of sulphur. A is dissolved in water to give an acid. The basicity of this acid is….
View answer and explanation
Correct option: A
2
Option A (2) is correct because when iron sulphide is heated in air, it forms sulphur dioxide, which dissolves in water to form sulphuric acid (H2SO4{H_2}S{O_4}), a dibasic acid.
40 Medium
40 of 93
Understanding +4 | -1
Sulphuric acid has great affinity for water because
View answer and explanation
Correct option: C
Acid forms hydrates with water
Option C (Acid forms hydrates with water) is correct because the dissolution of sulphuric acid in water is highly exothermic due to the formation of hydrates, releasing a large amount of energy.
41 Medium
41 of 93
Analyzing +4 | -1
Oxide of a non-metal possesses the following characteristics: (i) It is both a proton donor and proton acceptor. (ii) It is poor conductor of electricity. (iii) It reacts readily with basic and acidic oxides. (iv) It oxidses Fe at boiling point. The oxide is:
View answer and explanation
Correct option: A
H2O{H_2}O
Option A (H2O{H_2}O) is correct because water is amphoteric (proton donor and acceptor), a poor conductor of electricity, reacts with both acidic and basic oxides, and oxidizes Fe at boiling point.
42 Medium
42 of 93
Application +4 | -1
One mole of fluorine is reacted with two moles of hot and concentrated KOH. The products formed are KF H2O{H_2}O and O2{O_2}. The molar ratio of KF, H2O{H_2}O and O2{O_2} respectively is:
View answer and explanation
Correct option: B
0.084033565
Option B (0.084033565) is correct because the molar ratio of KF, H2OH_2O, and O2O_2 is 2:1:1, and the balanced equation is F2+2KOH→2KF+H2O+12O2F_2 + 2KOH \rightarrow 2KF + H_2O + \frac{1}{2}O_2.
43 Medium
43 of 93
Understanding +4 | -1
Minimum melting point among the following is of
View answer and explanation
Correct option: B
PH3P{H_3}
Option B (PH3P{H_3}) is correct because melting point generally increases down the group for these hydrides, but NH3N{H_3} has higher melting point due to hydrogen bonding, and PH3P{H_3} has the lowest melting point among the remaining options.
44 Medium
44 of 93
Analyzing +4 | -1
Which of the following statements is not valid for oxoacids of phosphorous
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Correct option: B
Hypophosphorous acid is a diprotic acid
Option B is correct because Hypophosphorous acid is a monoprotic acid, not a diprotic acid, due to the presence of two P-H bonds and one P-OH bond.
45 Medium
45 of 93
Understanding +4 | -1
The bond angle in PH3\mathrm{P}{\mathrm{H}_3} is:
View answer and explanation
Correct option: A
Much lesser than NH3\mathrm{N}{\mathrm{H}_3}
Option A (Much lesser than NH3\mathrm{N}{\mathrm{H}_3}) is correct because the bond angle in PH3P{H_3} is closer to 90 degrees due to less s-character in the bonding orbitals compared to NH3N{H_3}.
46 Medium
46 of 93
Remembering +4 | -1
The function of Fe(OH)3Fe{\left( {OH} \right)_3} in the contact process is
View answer and explanation
Correct option: A
To remove arsenic impurity
Option A (To remove arsenic impurity) is correct because Fe(OH)3Fe(OH)_3 is used to adsorb arsenic impurities in the Contact process for sulfuric acid production.
47 Medium
47 of 93
Application +4 | -1
If two litre of air is passed repeatedly over heated copper and heated Mg till no further reduction in volume takes place, the volume finally obtained will be approximately:
View answer and explanation
Correct option: B
20 mL
Option A (200 mL) is correct because oxygen and nitrogen are removed, leaving mostly noble gases and some residual gases.
48 Medium
48 of 93
Remembering +4 | -1
The gases absorbed by alkaline pyrogallol and oil of turpentine respectively are:
View answer and explanation
Correct option: B
O2,  O3{\mathrm{O}_2},\mathrm{\;}{\mathrm{O}_3}
Option B (O2,  O3{\mathrm{O}_2},\;{\mathrm{O}_3}) is correct because alkaline pyrogallol absorbs oxygen (O2) and oil of turpentine absorbs ozone (O3).
49 Medium
49 of 93
Remembering +4 | -1
Orthophosphoric acid on heating gives:
View answer and explanation
Correct option: D
Metaphosphoric acid
Option D (Metaphosphoric acid) is correct because orthophosphoric acid (H3PO4H_3PO_4) loses water upon heating to form metaphosphoric acid (HPO3HPO_3).
50 Medium
50 of 93
Analyzing +4 | -1
Which of the following halogen oxides is ionic?
View answer and explanation
Correct option: A
I4O9{\mathrm{I}_4}{\mathrm{O}_9}
Option A (I4O9{\mathrm{I}_4}{\mathrm{O}_9}) is the correct answer because iodine can exhibit a +9 oxidation state only in ionic compounds.
51 Medium
51 of 93
Understanding +4 | -1
Which is the correct thermal stability order for H2E (E = O, S, Se, Te and Po)?{H_2}E\,(E\, = \,O,\,S,\,Se,\,Te\,\mathrm{and}\,Po)?
View answer and explanation
Correct option: C
H2PO < H2Te < H2Se < H2S < H2O{H_2}PO\, < \,{H_2}Te\, < \,{H_2}Se\, < \,{H_2}S\, < \,{H_2}O
Option C (H2PO<H2Te<H2Se<H2S<H2O{H_2}PO < {H_2}Te < {H_2}Se < {H_2}S < {H_2}O) is correct because thermal stability decreases down the group due to decreasing bond dissociation energy.
52 Medium
52 of 93
Analyzing +4 | -1
The correct order of acidic nature is:
View answer and explanation
Correct option: A
Cl2O7>SO2>P4O10\mathrm{C}{\mathrm{l}_2}{\mathrm{O}_7} > \mathrm{S}{\mathrm{O}_2} > {\mathrm{P}_4}{\mathrm{O}_{10}}
Option A is correct because acidic nature of oxides increases with the electronegativity of the central atom and oxidation state.
53 Medium
53 of 93
Understanding +4 | -1
Product which is not obtained on the reaction of white phosphorous with thionyl chloride is
View answer and explanation
Correct option: D
POCl3POC{l_3}
Option D (POCl3POC{l_3}) is correct because the reaction of white phosphorus with thionyl chloride (SOCl2SOCl_2) produces PCl3PC{l_3}, SO2S{O_2}, and S2Cl2{S_2}C{l_2}, but not POCl3POC{l_3}.
54 Medium
54 of 93
Analyzing +4 | -1
The electronic configurations of four elements are given below. Which element does not belong to the same family as others?
View answer and explanation
Correct option: C
[Ne]3s2,  3p5\left[ {\mathrm{Ne}} \right]3{s^2},\mathrm{\;}3{p^5}
Option C ([Ne]3s², 3p⁵) is correct because it represents a halogen, while the others belong to the same family (transition metals or group 2).
55 Medium
55 of 93
Application +4 | -1
4NH3+5O2→6H2O+4NO.4N{H_3} + 5{O_2} \to 6{H_2}O + 4NO. On taking one mole of NH3N{H_3} and one mole of oxygen.
View answer and explanation
Correct option: A
Oxygen is completely reacted
Option A (Oxygen is completely reacted) is correct because, based on the stoichiometry of the reaction, oxygen is the limiting reagent when one mole of each reactant is taken.
56 Medium
56 of 93
Remembering +4 | -1
Chlorine acts as a bleaching agent only in presence of
View answer and explanation
Correct option: B
Moisture
Option B is correct. Chlorine acts as a bleaching agent only in the presence of moisture because it forms hypochlorous acid (HOCl), which is the active bleaching agent.
57 Medium
57 of 93
Application +4 | -1
Iodine reacts with concentrated HNO3HN{O_3} to yield Y along with other products. The oxidation state of iodine in Y,Y, is
View answer and explanation
Correct option: D
5
Option C (7) is correct because iodine reacts with concentrated nitric acid to form iodic acid (HIO3HIO_3), where the oxidation state of iodine is +5. The question asks for the oxidation state of I in Y, where Y is HIO3HIO_3. The reaction is I2+10HNO3→2HIO3+10NO2+4H2OI_2 + 10HNO_3 \rightarrow 2HIO_3 + 10NO_2 + 4H_2O. Thus, Y is HIO3HIO_3 and the oxidation state of I is +5.
58 Medium
58 of 93
Understanding +4 | -1
The final product of hydrolysis of XeF6Xe{F_6} is
View answer and explanation
Correct option: C
XeO3Xe{O_3}
Option C (XeO3XeO_3) is correct because XeF6XeF_6 undergoes complete hydrolysis to form XeO3XeO_3 and HF.
59 Medium
59 of 93
Analyzing +4 | -1
The spectrum of helium is similar to:
View answer and explanation
Correct option: B
Na
Option C (Li+L{i^ + }) is correct because both Helium and Li+Li^+ have 2 electrons and thus have similar electronic structures and spectra.
60 Medium
60 of 93
Remembering +4 | -1
Which of the following pairs is obtained on heating ammonium dichromate?
View answer and explanation
Correct option: A
N2 and H2O{\mathrm{N}_\mathrm{2}}\,\mathrm{and}\,\mathrm{ }{\mathrm{H}_\mathrm{2}}\mathrm{O}
Option A is correct. Heating ammonium dichromate (NH4)2Cr2O7 produces nitrogen gas (N2) and water (H2O) along with chromium(III) oxide (Cr2O3).
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