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NEET • CHEMISTRY • P-BLOCK ELEMENTS
P-block elements practice · Medium
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Showing 31-60 of 93 questions
31
Medium
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Application
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reacts with and to form ionic compounds and The geometry of ion and ion, respectively, is:
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Correct option: B
Bent T-shaped, square pyramidal
Option B (Bent T-shaped, square pyramidal) is correct because the geometries of and are bent T-shaped and square pyramidal, respectively, based on VSEPR theory.
32
Medium
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Understanding
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At ordinary temperature and pressure, among halogens, the chlorine is a gas, bromine is a liquid and iodine is a solid. This is because:
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Correct option: A
The specific heat is in the order
Option B (Intermolecular forces among molecules of chlorine are the weakest and those in iodine are the strongest) is correct because the physical state of halogens at room temperature depends on the strength of intermolecular forces, which increase with molecular size.
33
Medium
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Remembering
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The substance used in Holme’s signal of the ship is a mixture of
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Correct option: A
Option A () is correct because the mixture of calcium carbide and calcium phosphide produces acetylene and phosphine, which ignite spontaneously and produce a bright light, used as a signal on ships.
34
Medium
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Application
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can be distinguished by the addition of:
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Correct option: B
Option B () is correct because can oxidize to , while cannot reduce to .
35
Medium
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Understanding
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Stability of hydrides generally increases with:
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Correct option: A
Increase in bond angle
Option A (Increase in bond angle) is correct because as the bond angle increases, the s-character in the bonding orbitals increases, leading to greater stability.
36
Medium
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Analyzing
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A salt X gives white precipitates with lead acetate solution, insoluble in hot water and nitric acid. The salt X most probably contains:
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Correct option: C
Option C () is correct because lead sulfate () is a white precipitate insoluble in hot water and nitric acid.
37
Medium
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Application
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The oxidation states of in the following compounds are respectively be
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Correct option: A
Option A (+3, +3, -3, +5, +5) is correct because it accurately represents the oxidation states of P in each compound, calculated based on electronegativity differences and charge neutrality.
38
Medium
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Analyzing
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Which of the following reaction gives a gas which act as oxidising agent as well as reducing agent :
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Correct option: A
Option A () is correct because the reaction produces , which can act as both an oxidizing and reducing agent.
39
Medium
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Application
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Iron sulphide is heated in air to form A. an oxide of sulphur. A is dissolved in water to give an acid. The basicity of this acid is….
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Correct option: A
2
Option A (2) is correct because when iron sulphide is heated in air, it forms sulphur dioxide, which dissolves in water to form sulphuric acid (), a dibasic acid.
40
Medium
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Understanding
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Sulphuric acid has great affinity for water because
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Correct option: C
Acid forms hydrates with water
Option C (Acid forms hydrates with water) is correct because the dissolution of sulphuric acid in water is highly exothermic due to the formation of hydrates, releasing a large amount of energy.
41
Medium
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Analyzing
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Oxide of a non-metal possesses the following characteristics: (i) It is both a proton donor and proton acceptor. (ii) It is poor conductor of electricity. (iii) It reacts readily with basic and acidic oxides. (iv) It oxidses Fe at boiling point. The oxide is:
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Correct option: A
Option A () is correct because water is amphoteric (proton donor and acceptor), a poor conductor of electricity, reacts with both acidic and basic oxides, and oxidizes Fe at boiling point.
42
Medium
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Application
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One mole of fluorine is reacted with two moles of hot and concentrated KOH. The products formed are KF and . The molar ratio of KF, and respectively is:
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Correct option: B
0.084033565
Option B (0.084033565) is correct because the molar ratio of KF, , and is 2:1:1, and the balanced equation is .
43
Medium
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Understanding
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Minimum melting point among the following is of
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Correct option: B
Option B () is correct because melting point generally increases down the group for these hydrides, but has higher melting point due to hydrogen bonding, and has the lowest melting point among the remaining options.
44
Medium
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Analyzing
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Which of the following statements is not valid for oxoacids of phosphorous
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Correct option: B
Hypophosphorous acid is a diprotic acid
Option B is correct because Hypophosphorous acid is a monoprotic acid, not a diprotic acid, due to the presence of two P-H bonds and one P-OH bond.
45
Medium
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Understanding
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The bond angle in is:
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Correct option: A
Much lesser than
Option A (Much lesser than ) is correct because the bond angle in is closer to 90 degrees due to less s-character in the bonding orbitals compared to .
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46
Medium
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Remembering
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The function of in the contact process is
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Correct option: A
To remove arsenic impurity
Option A (To remove arsenic impurity) is correct because is used to adsorb arsenic impurities in the Contact process for sulfuric acid production.
47
Medium
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Application
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If two litre of air is passed repeatedly over heated copper and heated Mg till no further reduction in volume takes place, the volume finally obtained will be approximately:
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Correct option: B
20 mL
Option A (200 mL) is correct because oxygen and nitrogen are removed, leaving mostly noble gases and some residual gases.
48
Medium
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Remembering
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The gases absorbed by alkaline pyrogallol and oil of turpentine respectively are:
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Correct option: B
Option B () is correct because alkaline pyrogallol absorbs oxygen (O2) and oil of turpentine absorbs ozone (O3).
49
Medium
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Remembering
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Orthophosphoric acid on heating gives:
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Correct option: D
Metaphosphoric acid
Option D (Metaphosphoric acid) is correct because orthophosphoric acid () loses water upon heating to form metaphosphoric acid ().
50
Medium
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Analyzing
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Which of the following halogen oxides is ionic?
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Correct option: A
Option A () is the correct answer because iodine can exhibit a +9 oxidation state only in ionic compounds.
51
Medium
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Understanding
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Which is the correct thermal stability order for
View answer and explanation
Correct option: C
Option C () is correct because thermal stability decreases down the group due to decreasing bond dissociation energy.
52
Medium
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Analyzing
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The correct order of acidic nature is:
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Correct option: A
Option A is correct because acidic nature of oxides increases with the electronegativity of the central atom and oxidation state.
53
Medium
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Understanding
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Product which is not obtained on the reaction of white phosphorous with thionyl chloride is
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Correct option: D
Option D () is correct because the reaction of white phosphorus with thionyl chloride () produces , , and , but not .
54
Medium
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Analyzing
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The electronic configurations of four elements are given below. Which element does not belong to the same family as others?
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Correct option: C
Option C ([Ne]3s², 3p⁵) is correct because it represents a halogen, while the others belong to the same family (transition metals or group 2).
55
Medium
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Application
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On taking one mole of and one mole of oxygen.
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Correct option: A
Oxygen is completely reacted
Option A (Oxygen is completely reacted) is correct because, based on the stoichiometry of the reaction, oxygen is the limiting reagent when one mole of each reactant is taken.
56
Medium
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Remembering
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Chlorine acts as a bleaching agent only in presence of
View answer and explanation
Correct option: B
Moisture
Option B is correct. Chlorine acts as a bleaching agent only in the presence of moisture because it forms hypochlorous acid (HOCl), which is the active bleaching agent.
57
Medium
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Application
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Iodine reacts with concentrated to yield Y along with other products. The oxidation state of iodine in is
View answer and explanation
Correct option: D
5
Option C (7) is correct because iodine reacts with concentrated nitric acid to form iodic acid (), where the oxidation state of iodine is +5. The question asks for the oxidation state of I in Y, where Y is . The reaction is . Thus, Y is and the oxidation state of I is +5.
58
Medium
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Understanding
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The final product of hydrolysis of is
View answer and explanation
Correct option: C
Option C () is correct because undergoes complete hydrolysis to form and HF.
59
Medium
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Analyzing
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The spectrum of helium is similar to:
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Correct option: B
Na
Option C () is correct because both Helium and have 2 electrons and thus have similar electronic structures and spectra.
60
Medium
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Remembering
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Which of the following pairs is obtained on heating ammonium dichromate?
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Correct option: A
Option A is correct. Heating ammonium dichromate (NH4)2Cr2O7 produces nitrogen gas (N2) and water (H2O) along with chromium(III) oxide (Cr2O3).
Revision notes and key takeaways
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