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NEET • CHEMISTRY • CHEMICAL BONDING & MOLECULAR STRUCTURE
Chemical bonding & molecular structure practice · Mixed difficulty
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91
Medium
91 of 579
Understanding
+4 | -1
Which has the largest distance between the carbon hydrogen atom?
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Correct option: A
Ethane
Option A (Ethane) is correct because it has only single bonds, which are longer than the multiple bonds in ethene, ethyne, and the delocalized bonds in benzene.
92
Easy
92 of 579
Understanding
+4 | -1
Which one has more tendency to form covalent compounds?
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Correct option: B
Option B is correct because Be has a small size and high polarizing power, leading to a greater tendency to form covalent compounds according to Fajans' rules.
93
Easy
93 of 579
Analyzing
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In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one?
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Correct option: C
Option C () is correct because NO is paramagnetic with a bond order of 2.5, while is diamagnetic with a bond order of 3.
94
Easy
94 of 579
Understanding
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Among the NaF has highest melting point because:
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Correct option: A
It has maximum ionic character
Option A (It has maximum ionic character) is correct because, according to Fajan's rule, smaller cation and anion size leads to higher lattice energy and thus a higher melting point, and NaF has the smallest ions among the given options.
95
Medium
95 of 579
Remembering
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Electron deficient species are known as:
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Correct option: A
Lewis acids
Option A is correct because electron-deficient species, which can accept electron pairs, are known as Lewis acids.
96
Medium
96 of 579
Remembering
+4 | -1
Covalent compounds are generally soluble in
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Correct option: B
Non-polar solvents
Option B (Non-polar solvents) is correct because \"like dissolves like,\" and covalent compounds are generally non-polar.
97
Easy
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Analyzing
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Which of the following compounds would have the highest boiling point?
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Correct option: C
Option C () is correct because alcohols exhibit hydrogen bonding, which significantly increases the boiling point compared to alkanes, amines, and haloalkanes.
98
Medium
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Remembering
+4 | -1
The half of the difference between the number of electrons in bonding molecular orbitals and antibonding molecular orbitals is known as:
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Correct option: A
Bond order
Option A (Bond order) is correct because bond order is defined as half the difference between the number of electrons in bonding molecular orbitals and antibonding molecular orbitals, indicating the stability of a chemical bond.
99
Easy
99 of 579
Understanding
+4 | -1
For a stable molecule, the value of bond order must be
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Correct option: C
Positive
Option C (Positive) is correct because a positive bond order indicates that there are more bonding electrons than antibonding electrons, resulting in a stable molecule.
100
Easy
100 of 579
Understanding
+4 | -1
Which shows the least dipole moment?
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Correct option: D
Option D is correct because CCl4 is a symmetrical tetrahedral molecule where the bond dipoles cancel out, resulting in a zero dipole moment.
101
Medium
101 of 579
Understanding
+4 | -1
From the molecular orbital theory, one can show that the bond order in molecule as
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Correct option: B
1
Option B (1) is correct because has a bond order of 1, indicating a single bond between the two fluorine atoms.
102
Medium
102 of 579
Analyzing
+4 | -1
Which of the following species has a bond order other than 3?
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Correct option: D
Option D () is correct because its bond order is 2.5, while the other options have a bond order of 3.
103
Hard
103 of 579
Analyzing
+4 | -1
Consider the following molecules or ions (i) ,(ii) ,(iii) ,(iv) ,(v) , hybridisation is involved in the formation of
View answer and explanation
Correct option: D
(i), (ii), (iii), (iv) and (v)
Option D ((i), (ii), (iii), (iv) and (v)) is correct because all the listed molecules/ions involve hybridization.
104
Hard
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Analyzing
+4 | -1
The dipole moment of diatomic molecules and are 10.41 and 10.27 Debye respectively while there bond distances are and respectively then
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Correct option: D
has lesser ionic bond character than
Option D ( has lesser ionic bond character than ) is correct because the percent ionic character is lower for AB compared to CD based on their dipole moments and bond distances.
105
Medium
105 of 579
Remembering
+4 | -1
The observed bond length in ozone molecule is
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Correct option: C
Option C () is correct because the observed O-O bond length in ozone is 128 pm due to resonance.
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106
Easy
106 of 579
Application
+4 | -1
The number of anti-bonding electron pairs in ion is
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Correct option: A
4
Option A (4) is correct because in , there are 8 antibonding electrons, which equals 4 antibonding pairs.
107
Medium
107 of 579
Application
+4 | -1
The electronegativity of and are , 3.0 and 2.1 respectively. The strongest bond will be:
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Correct option: D
Option D () is correct because the electronegativity difference between O and H is the greatest among the given options, leading to the strongest and most polar bond.
108
Medium
108 of 579
Remembering
+4 | -1
Which of these statements is correct according to VBT?
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Correct option: B
Covalent bond is formed by partial overlap of two half-filled atomic orbitals containing electrons in opposite
spin
spin
Option B (Covalent bond is formed by partial overlap of two half-filled atomic orbitals containing electrons in opposite spin) is correct because VBT states that a covalent bond forms from the partial overlap of two half-filled atomic orbitals with electrons of opposite spin.
109
Easy
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Analyzing
+4 | -1
-character of bond is maximum in :
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Correct option: A
Option A () is correct because in diazene (), the nitrogen atom is sp hybridized, resulting in 50% s-character in the N-H bond, which is higher than in and .
110
Easy
110 of 579
Understanding
+4 | -1
The maximum valency of an element with atomic number 7 is
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Correct option: D
5
Option D is correct because the maximum valency of an element is determined by the total number of valence electrons and unpaired electrons it can use for bonding. Nitrogen (atomic number 7) has 5 valence electrons.
111
Easy
111 of 579
Application
+4 | -1
Oxidation state of three carbon atoms in are
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Correct option: B
Option B () is correct because the central carbon has an oxidation state of 0, while the terminal carbons each have an oxidation state of +2.
112
Medium
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Application
+4 | -1
Which of the following molecular species has unpaired electron (s)?
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Correct option: C
Option C () is correct because it has an odd number of electrons, leading to unpaired electron(s).
113
Easy
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Analyzing
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Assertion (A): is resonance stabilized molecule.
Reason (R): Bond length of in is intermediate of single and double bond length.
Reason (R): Bond length of in is intermediate of single and double bond length.
View answer and explanation
Correct option: C
(A) is true but (R) is false
Option C ((A) is true but (R) is false) is correct because is resonance stabilized, but the C-O bond length is not intermediate between a single and double bond; it's intermediate between a double and triple bond.
114
Medium
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Analyzing
+4 | -1
Which of the following is false?
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Correct option: D
Acetylene is non-linear
Option D (Acetylene is non-linear) is correct because acetylene (C₂H₂) is linear due to the sp hybridization of the carbon atoms.
115
Easy
115 of 579
Application
+4 | -1
Which bond is more polar?
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Correct option: C
Option C () is correct because the electronegativity difference between carbon and fluorine is the largest among the given options.
116
Hard
116 of 579
Analyzing
+4 | -1
How many species do not exist?
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Correct option: A
8
Option A (8) is correct because there are 8 species that do not exist due to various reasons such as exceeding the octet rule or steric hindrance.
117
Easy
117 of 579
Understanding
+4 | -1
According to MO theory
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Correct option: A
is paramagnetic and B.O is greater than
Option A ( is paramagnetic and B.O is greater than ) is correct because has one less electron in an antibonding orbital, making it paramagnetic with a higher bond order than .
118
Easy
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Understanding
+4 | -1
The ICl molecule is:
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Correct option: C
Polar with negative end on chlorine
Option D (Polar with negative end on chlorine) is correct because chlorine is more electronegative than iodine, so the ICl molecule is polar with a partial negative charge on chlorine.
119
Easy
119 of 579
Analyzing
+4 | -1
Given below are two statements: one is labeled as Assertion (A) and the other is labeled as Reason (R).
Assertion (A) Dipole –dipole interactions are the only non-covalent interactions, resulting in hydrogen bond formation.
Reason (R) Fluorine is the most electronegative element and hydrogen bonds in are symmetrical.
In the light of the above statements, choose the most appropriate answer from the options given below.
Assertion (A) Dipole –dipole interactions are the only non-covalent interactions, resulting in hydrogen bond formation.
Reason (R) Fluorine is the most electronegative element and hydrogen bonds in are symmetrical.
In the light of the above statements, choose the most appropriate answer from the options given below.
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Correct option: A
A is false but R is true.
Option A (A is false but R is true) is correct because dipole-dipole interactions are not the ONLY non-covalent interactions resulting in hydrogen bond formation, and Fluorine is indeed the most electronegative element, leading to symmetrical hydrogen bonds in HF.
120
Easy
120 of 579
Analyzing
+4 | -1
Among the following compounds the one that is polar and has central atom with -hybridisation is:
View answer and explanation
Correct option: A
Option A () is correct because it is polar and the central carbon atom is hybridized.
Revision notes and key takeaways
Review CHEMICAL BONDING & MOLECULAR STRUCTURE in your textbook or class notes, then use this set to check your understanding.
Showing 91-120 of 579 questions
