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JEE • CHEMISTRY • SOLUTIONS

Solutions practice · Easy

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These sets use single-correct-answer MCQs. They do not cover every JEE Main or JEE Advanced question format and are not full-length mock papers.

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Showing 91-118 of 118 questions
91 Easy
91 of 118
Application +4 | -1
The osmotic pressure of a non-volatile solute in C6H6\mathrm{C}_6 {H}_6 at 25∘C25^{\circ} {C} is 20.66Nm−220.66 {Nm}^{-2}. If the solution had a concentration of 2 g/dm32 {~g} / {dm}^3, what is molar mass of solute?
View answer and explanation
Correct option: A
239.84
Option A (239.84) is correct because it is the molar mass calculated using the osmotic pressure formula.
92 Easy
92 of 118
Application +4 | -1
5 L of a solution contains 25 mg of CaCO3.CaC{O_3}. What is its concentration in ppm? (mol. wt. of CaCO3CaC{O_3} is 100)
View answer and explanation
Correct option: C
5
Option B (5) is correct because the concentration in ppm is calculated as (mass of solute / mass of solution) * 106, which equals 5 ppm.
93 Easy
93 of 118
Analyzing +4 | -1
When Hgl2{Hgl}_2 is added to an aqueous solution of Kl{Kl}
View answer and explanation
Correct option: A
The vapour pressure of solution increases
Option A (The vapour pressure of solution increases) is correct because the formation of a complex reduces the number of free ions in the solution, leading to an increase in vapor pressure.
94 Easy
94 of 118
Understanding +4 | -1
During depression of freezing point in a solution the following are in equilibrium
View answer and explanation
Correct option: A
Liquid solvent, solid solvent
Option A (Liquid solvent, solid solvent) is correct because during the depression of freezing point, the liquid solvent is in equilibrium with the solid solvent.
95 Easy
95 of 118
Analyzing +4 | -1
ASSERTION : Molar heat of vaporisation of water is greater than benzene.

REASON : Molar heat of vaporisation is the amount of heat required to vaporise one mole of liquid at constant temperature.
View answer and explanation
Correct option: B
If both AA and RR are correct but RR is not correct explanation of AA.
Option B is correct. Both the assertion and reason are correct, but the reason doesn't correctly explain the assertion. The intermolecular forces are stronger in water than benzene.
96 Easy
96 of 118
Understanding +4 | -1
The ratio of vapour pressure over solution phase on mixing two immiscible liquids is equal to :
View answer and explanation
Correct option: D
Ration of their moles in vapour phase
The correct answer is D (Ration of their moles in vapour phase) because the ratio of vapor pressures of immiscible liquids is equal to the ratio of their mole fractions in the vapor phase.
97 Easy
97 of 118
Application +4 | -1
According to phase rule, if P=3,C=1,P = 3,C = 1, then F must be equal to :
View answer and explanation
Correct option: C
Zero
Option C (Zero) is correct because, according to the phase rule, F = C - P + 2, and substituting P = 3 and C = 1 gives F = 1 - 3 + 2 = 0.
98 Easy
98 of 118
Remembering +4 | -1
Aqueous solutions of two acids having same concentrations of common ion [H+]\left[ {{\mathrm{H}^ + }} \right] are called:
View answer and explanation
Correct option: A
Isohydric solutions
Option A (Isohydric solutions) is correct because Isohydric solutions are defined as solutions of two or more substances having the same hydrogen ion concentration ([H+]).
99 Easy
99 of 118
Understanding +4 | -1
A liquid is in equilibrium with its vapours at its boiling point. On the average the molecules in the two phases have equal :
View answer and explanation
Correct option: C
Kinetic energy
Option C (Kinetic energy) is correct because at the boiling point, the average kinetic energy of the molecules in the liquid and vapor phases are equal, as temperature is a measure of average kinetic energy.
100 Easy
100 of 118
Understanding +4 | -1
The amalgam of mercury in sodium is an example of
View answer and explanation
Correct option: C
Liquid in solid solution
Option C (Liquid in solid solution) is correct because mercury is a liquid and sodium is a solid, and in an amalgam, the liquid mercury is dispersed within the solid sodium.
101 Easy
101 of 118
Understanding +4 | -1
The reverse of fusion is freezing and it is :
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Correct option: B
Exothermic
Option B (Exothermic) is correct because freezing is the reverse of fusion, and since fusion is endothermic (requires heat), freezing must be exothermic (releases heat).
102 Easy
102 of 118
Analyzing +4 | -1
Select the incorrect statement :
View answer and explanation
Correct option: D
For isotonic solutions C1C_1 must be equal to C2C_2.
Option D is the incorrect statement because for isotonic solutions, the concentrations C1C_1 and C2C_2 must be equal only when the solutes neither dissociate nor associate.
103 Easy
103 of 118
Analyzing +4 | -1
Which of the following has minimum freezing point?
View answer and explanation
Correct option: D
0.1 M Al2(SO4)30.1 \mathrm{~M} \mathrm{~Al}_2\left(\mathrm{SO}_4\right)_3
Option D (0.1 M Al2(SO4)30.1 \mathrm{~M} \mathrm{~Al}_2\left(\mathrm{SO}_4\right)_3) is correct because it dissociates into the largest number of ions (5 ions per formula unit), leading to the greatest depression in freezing point.
104 Easy
104 of 118
Understanding +4 | -1
The vapour pressure (VP)(VP) of a dilute solution of non-volatile solute is PP and the VPVP of pure solvent is P0{P_0}, the lowering of the VPVP is :
View answer and explanation
Correct option: A
#NAME?
Option A (P0−PP_0 - P) is correct because the lowering of vapor pressure is defined as the difference between the vapor pressure of the pure solvent and the vapor pressure of the solution.
105 Easy
105 of 118
Remembering +4 | -1
A thermometer which can be used only for accurate measurement of small differences in temperature is known as a:
View answer and explanation
Correct option: A
Beckmann thermometer
Option A (Beckmann thermometer) is correct because a Beckmann thermometer is designed for accurate measurement of small temperature differences.
106 Easy
106 of 118
Analyzing +4 | -1
An aqueous solution is 1.0 molal in KI. Which change will cause the vapour pressure of solution to increase :
View answer and explanation
Correct option: D
Addition of water
Option D (Addition of water) is correct because adding water increases the mole fraction of the solvent, thereby increasing the vapor pressure of the solution.
107 Easy
107 of 118
Understanding +4 | -1
A solute is soluble in two immiscible liquids which are present in a mixture. The concentration of the solute in the upper layer will be :
View answer and explanation
Correct option: D
In fixed ratio with that in the lower layer
Option D (In fixed ratio with that in the lower layer) is correct because the distribution law states that the ratio of concentrations of a solute in two immiscible liquids is constant at a given temperature.
108 Easy
108 of 118
Application +4 | -1
Which has the minimum freezing point?
View answer and explanation
Correct option: B
One molal CaCl2CaC{l_2} aqueous solution
Option B (One molal CaCl2CaCl_2 aqueous solution) is correct because depression in freezing point is a colligative property, and CaCl2CaCl_2 dissociates into 3 ions, resulting in the greatest depression in freezing point compared to the other options.
109 Easy
109 of 118
Understanding +4 | -1
The solubility of a solid in a liquid depends on :
View answer and explanation
Correct option: D
All of these
Option D (All of these) is correct because the solubility of a solid in a liquid is influenced by the nature of both the solute and solvent, as well as the temperature.
110 Easy
110 of 118
Application +4 | -1
A dry air is passed through the solution, containing the 10 g10 \mathrm{~g} of solute and 90 g90 \mathrm{~g} of water and then it is passed through pure water. There is the depression in weight of solution by 2.5 g2.5 \mathrm{~g} and in weight of pure solution by 0.05 g0.05 \mathrm{~g}. Calculate the molecular weight of solute.
View answer and explanation
Correct option: C
100
Option C (100) is correct because the molecular weight of the solute is calculated using Raoult's Law, relating the vapor pressure lowering to the mole fraction of the solute.
111 Easy
111 of 118
Analyzing +4 | -1
Assertion (A): Isotonic solutions must have same elevation in boiling point.

Reason (R): Osmotic pressure, π=iCRT\pi=i C R T
View answer and explanation
Correct option: D
A is false, R is true
Option D (A is false, R is true) is correct because isotonic solutions have the same osmotic pressure, not necessarily the same elevation in boiling point, and the reason correctly states the formula for osmotic pressure.
112 Easy
112 of 118
Application +4 | -1
The vapour pressure of water at room temperature is lowered by 5%5 \% on dissolving a non-volatile solute in it. The molality of the solution is
View answer and explanation
Correct option: D
2.92
Option D (2.92) is correct because it is calculated using the relative lowering of vapor pressure formula and Raoult's law.
113 Easy
113 of 118
Analyzing +4 | -1
Maximum freezing point will be for 1 molal solution, assuming equal ionization in each case:
View answer and explanation
Correct option: D
[Fe(H2O)3Cl3]⋅3H2O\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{Cl}_3\right] \cdot 3 \mathrm{H}_2 \mathrm{O}
The correct answer is D because [Fe(H2O)3Cl3]⋅3H2O\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{Cl}_3\right] \cdot 3 \mathrm{H}_2 \mathrm{O} will give the least number of ions in solution, resulting in the smallest depression in freezing point and thus the maximum freezing point.
114 Easy
114 of 118
Understanding +4 | -1
Which of the following is correct for a solution showing positive deviations from Raoult's law?
View answer and explanation
Correct option: A
ΔV=+ve,ΔH=+ve\Delta \mathrm{V}=+\mathrm{ve}, \Delta \mathrm{H}=+\mathrm{ve}
Option A (ΔV=+ve,ΔH=+ve\Delta \mathrm{V}=+\mathrm{ve}, \Delta \mathrm{H}=+\mathrm{ve}) is correct because for solutions showing positive deviations from Raoult's law, the volume and enthalpy changes upon mixing are positive, indicating weaker intermolecular forces in the solution compared to the pure components.
115 Easy
115 of 118
Understanding +4 | -1
Van’t Hoff factor more than unity indicates that the solute in solution has
View answer and explanation
Correct option: A
Dissociated
Option A (Dissociated) is correct because a Van't Hoff factor greater than 1 indicates that the number of particles in solution has increased due to dissociation of the solute.
116 Easy
116 of 118
Application +4 | -1
What is the total number of moles of H2SO4{H_2}S{O_4} needed to prepare 5.0  L5.0\;L of a 2.0  M2.0\;M solution of H2SO4{H_2}S{O_4} ?
View answer and explanation
Correct option: C
10
Option C (10) is correct because the number of moles is calculated by multiplying the molarity of the solution by its volume in liters: 2.0 M * 5.0 L = 10 moles.
117 Easy
117 of 118
Understanding +4 | -1
Maximum lowering of vapour pressure is observed in the case of
View answer and explanation
Correct option: B
0.1  M  BaCl20.1\;M\;BaC{l_2}
Option B (0.1 M BaCl2BaCl_2) is correct because it dissociates into the largest number of ions (3), leading to the maximum lowering of vapor pressure, which is a colligative property.
118 Easy
118 of 118
Application +4 | -1
The solubility of a specific non-volatile salt is 4 g4 \mathrm{~g} in 100 g100 \mathrm{~g} of water at 25∘C25^{\circ} \mathrm{C}. If 2.0 g,4.0 g2.0 \mathrm{~g}, 4.0 \mathrm{~g} and 6.0 g6.0 \mathrm{~g} of the salt added of 100 g100 \mathrm{~g} of water at 25∘C25^{\circ} \mathrm{C}, in system X,YX, Y and ZZ. The vapour pressure would be in the order:
View answer and explanation
Correct option: D
X>Y=ZX > Y = Z
Option D (X>Y=ZX > Y = Z) is correct because the vapor pressure of an unsaturated solution (X) is higher than that of a saturated solution (Y and Z), and saturated solutions have the same vapor pressure regardless of the amount of undissolved solute.
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