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JEE • CHEMISTRY • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES
Organic chemistry-some basic principles and techniques practice · Mixed difficulty
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211
Easy
211 of 345
Understanding
+4 | -1
The effect is shown by :
View answer and explanation
Correct option: A
Option A () is correct because carboxylic acid groups are electron-withdrawing and exhibit a -I effect.
212
Easy
212 of 345
Understanding
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Which of the following molecules contain asymmetric carbon atom?
View answer and explanation
Correct option: A
Option A is correct because the second carbon in CH3CHClCOOH is bonded to four different groups (H, Cl, CH3, COOH), making it a chiral center.
213
Medium
213 of 345
Remembering
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Anthracene is purified by:
View answer and explanation
Correct option: D
Sublimation
Option D (Sublimation) is correct because Anthracene can be purified by sublimation due to its ability to transition directly from solid to gas phase.
214
Medium
214 of 345
Analyzing
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Assertion (A): Pyrrole, is aromatic and undergoes electrophilic aromatic substitution extremely readily and predominant by at position adjacent to nitrogen.
Reason (R): Nitrogen in the ring bearing a lone pair in conjugation with -electrons brings aromaticity to the pyrrole.
Reason (R): Nitrogen in the ring bearing a lone pair in conjugation with -electrons brings aromaticity to the pyrrole.
View answer and explanation
Correct option: B
Both (A) & (R) are true but the (R) is not the correct explanation of the (A)
The correct answer is B because both the assertion and reason are true, but the reason doesn't fully explain why electrophilic substitution occurs predominantly at the position adjacent to nitrogen.
215
Easy
215 of 345
Understanding
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Example of chain isomerism are
View answer and explanation
Correct option: C
pentanoic acid and 2 – methyl butanoic acid
Option C (pentanoic acid and 2 – methyl butanoic acid) is correct because they have the same molecular formula but differ in the arrangement of the carbon chain.
216
Easy
216 of 345
Understanding
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The maximum bond energy is present
View answer and explanation
Correct option: A
Option A () is correct because the C-H bond generally has the highest bond energy among the given options due to the smaller size and higher electronegativity of hydrogen.
217
Easy
217 of 345
Remembering
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The IUPAC suffix name of is:
View answer and explanation
Correct option: A
Oyl halide
Option A (Oyl halide) is correct because the IUPAC suffix for acyl halides (-COX) is 'oyl halide'.
218
Easy
218 of 345
Application
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Which of the following molecules represents the order of hybridization from left to right atoms.
View answer and explanation
Correct option: B
Option B () is correct because it correctly assigns , , , and hybridization to the carbon atoms from left to right.
219
Easy
219 of 345
Remembering
+4 | -1
The energy difference between the chair and boat form of cyclohexane is :
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Correct option: A
44 kJ
Option A (44 kJ ) is correct because the energy difference between the chair and boat form of cyclohexane is 44 kJ .
220
Medium
220 of 345
Analyzing
+4 | -1
The number of asymmetric -atom created and number of possible stereoisomers when benzil is reduced with .
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Correct option: A
2,3
Option A (2,3) is correct because the reduction of benzil with LiAlH4 creates two chiral carbon atoms, leading to three stereoisomers (two enantiomers and one meso compound).
221
Medium
221 of 345
Understanding
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Assertion (A): Simple distillation can help in separating a mixture of propan-1-ol (boiling point and propanone (boiling point
Reason (R): Liquids with a difference of more than in their boiling points can be separated by simple distillation.
Reason (R): Liquids with a difference of more than in their boiling points can be separated by simple distillation.
View answer and explanation
Correct option: A
Both (A) & (R) are true and the (R) is the correct explanation of the (A)
The correct answer is A (Both (A) & (R) are true and the (R) is the correct explanation of the (A)) because simple distillation is effective for separating liquids with a significant difference in boiling points.
222
Hard
222 of 345
Analyzing
+4 | -1
The correct decreasing order of acidic strength
of (A) trichloroacetic acid, (B) trifluoroacetic acid, (C) acetic acid, (D) formic acid is
of (A) trichloroacetic acid, (B) trifluoroacetic acid, (C) acetic acid, (D) formic acid is
View answer and explanation
Correct option: C
B A D C
The correct answer is C because the electron-withdrawing effect of fluorine is greater than chlorine, and both are greater than hydrogen, leading to the acidity order B > A > D > C.
223
Medium
223 of 345
Analyzing
+4 | -1
Identify, which of the below does not possess any element of symmetry?
View answer and explanation
Correct option: A
(+)(-) tartaric acid
Option A ((+)(-) tartaric acid) is correct because a racemic mixture of tartaric acid does not possess any element of symmetry.
224
Easy
224 of 345
Understanding
+4 | -1
Out of following which is not property of homologous series
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Correct option: C
same physical property
Option C (same physical property) is correct because while homologous series share the same functional group, chemical properties, and general formula, their physical properties vary due to differences in molecular weight.
225
Easy
225 of 345
Remembering
+4 | -1
Detection of sulphur in sodium extract is done by
View answer and explanation
Correct option: C
Both (a) and (b)
Option C (Both (a) and (b)) is correct because both lead acetate and sodium nitroprusside can be used to detect the presence of sulfur in a sodium extract.
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226
Medium
226 of 345
Understanding
+4 | -1
Compound that will give positive Lassaigne's test for both nitrogen and halogen is
View answer and explanation
Correct option: A
Option A () is correct because it contains both nitrogen and halogen, which will be detected in the Lassaigne's test.
227
Medium
227 of 345
Analyzing
+4 | -1
But-2-yne is reacted separately with one mole of Hydrogen as shown below
(A) A is more than soluble than B.
(B) The boiling point & melting point of A are higher and lower than B respectively.
(C) A is more polar than B because dipole moment of A is zero.
(D) adds easily to B than A.
Identify the incorrect statements from the option given below
(A) A is more than soluble than B.
(B) The boiling point & melting point of A are higher and lower than B respectively.
(C) A is more polar than B because dipole moment of A is zero.
(D) adds easily to B than A.
Identify the incorrect statements from the option given below
View answer and explanation
Correct option: B
B, C & D only
The correct answer is B (B, C & D only) because the boiling point of A (cis-But-2-ene) is higher than B (trans-But-2-ene), A is more polar than B, and adds more easily to A than B.
228
Easy
228 of 345
Remembering
+4 | -1
Which of the following is not a preliminary test used to detect ions?
View answer and explanation
Correct option: C
Brown ring test
Option C (Brown ring test) is correct because the brown ring test is a confirmatory test for nitrates, not a preliminary test.
229
Medium
229 of 345
Understanding
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Statement I : A tertiary carbocation is more stable than a secondary carbocation which is more stable than a primary carbocation
Statement II : The inductive effects operate through sigma bonds and decrease rapidly with increase in distance between the substituent and the reaction site
Statement II : The inductive effects operate through sigma bonds and decrease rapidly with increase in distance between the substituent and the reaction site
View answer and explanation
Correct option: C
Both statements are correct
Option C (Both statements are correct) is correct because tertiary carbocations are indeed more stable due to the inductive effect and hyperconjugation, and the inductive effect diminishes with distance.
230
Medium
230 of 345
Understanding
+4 | -1
The production of an optically active compound from a symmetric molecule without resolution in termed as :
View answer and explanation
Correct option: C
Asymmetric synthesis
Option C (Asymmetric synthesis) is correct because asymmetric synthesis is the production of an optically active compound from a symmetric molecule without resolution.
231
Medium
231 of 345
Understanding
+4 | -1
Arrange the Anions in decreasing order of their basic strength
View answer and explanation
Correct option: A
p q r s
Option A (p q r s) is correct because the basic strength of anions is inversely proportional to the acidic strength of their conjugate acids. The conjugate acids are , , , and , with increasing acidity, thus the basicity decreases in the order given.
232
Easy
232 of 345
Understanding
+4 | -1
Which of the following sodium compound/compounds are formed when an organic compound containing both nitrogen and sulphur is fused with sodium?
View answer and explanation
Correct option: B
Thiocyanate
Option B (Thiocyanate) is correct because when an organic compound containing both nitrogen and sulfur is fused with sodium, it forms sodium thiocyanate (NaSCN).
233
Medium
233 of 345
Analyzing
+4 | -1
Incorrect statement for the use of indicators in acid-base titration is :
View answer and explanation
Correct option: C
Methyl orange may be used for a weak acid vs weak base titration.
The correct answer is C (Methyl orange may be used for a weak acid vs weak base titration) because there is no suitable indicator for weak acid vs weak base titrations.
234
Medium
234 of 345
Analyzing
+4 | -1
The number of hybridized carbon atoms present in ‘Aspartame’ are
View answer and explanation
Correct option: C
9
Option C (9) is correct because the structure of Aspartame contains 9 carbon atoms with sp² hybridization.
235
Medium
235 of 345
Understanding
+4 | -1
Which of the following would be the best (most reactive) nucleophile in the polar medium?
View answer and explanation
Correct option: A
Option A () is the best nucleophile in a polar protic medium because larger ions are more polarizable and less solvated, making them more reactive.
236
Medium
236 of 345
Analyzing
+4 | -1
Which of the following statement(s) is/are correct ?
(i) A carbon atom having an hybrid orbital is less electronegative than carbon atoms possessing or hybridised orbitals.
(ii) -bonds provide the most reactive centres in the molecules containing multiple bonds
(iii) The number of and bonds in compound are 7 and 2 respectively.
(i) A carbon atom having an hybrid orbital is less electronegative than carbon atoms possessing or hybridised orbitals.
(ii) -bonds provide the most reactive centres in the molecules containing multiple bonds
(iii) The number of and bonds in compound are 7 and 2 respectively.
View answer and explanation
Correct option: C
(ii) only
The correct answer is C ((ii) only) because π-bonds are indeed reactive centers, while the other statements are incorrect regarding electronegativity and bond counts.
237
Medium
237 of 345
Understanding
+4 | -1
Arrange the following free radicals in order of decreasing stability.
Methyl (I), Vinyl (II), Allyl (III), Benzyl (IV)
Methyl (I), Vinyl (II), Allyl (III), Benzyl (IV)
View answer and explanation
Correct option: D
IV III I II
Option D (IV III I II) is correct because benzyl is most stable due to resonance, followed by allyl, methyl, and then vinyl due to resonance and hyperconjugation.
238
Easy
238 of 345
Understanding
+4 | -1
Isomerism exhibited by acetic acid and methyl formate is :
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Correct option: A
Functional
Option A (Functional) is correct because acetic acid and methyl formate have different functional groups (carboxylic acid and ester, respectively).
239
Easy
239 of 345
Analyzing
+4 | -1
Which one of the following does not have -hybridized carbon?
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Correct option: C
The correct answer is C () because the carbon atom bonded to the nitrogen atom is sp hybridized, not sp2.
240
Easy
240 of 345
Remembering
+4 | -1
Which method is used to separate sugars?
View answer and explanation
Correct option: C
Chromatography
Option C (Chromatography) is correct because chromatography is a technique used to separate sugars based on their different affinities for a stationary and mobile phase.
Revision notes and key takeaways
Review ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES in your textbook or class notes, then use this set to check your understanding.
Showing 211-240 of 345 questions
