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JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Choose the correct statements about the hydrides of group 15 elements.

A. The stability of the hydrides decreases in the order NH3>PH3>AsH3>SbH3>BiH3\mathrm{NH}_3 > \mathrm{PH}_3 > \mathrm{AsH}_3 > \mathrm{SbH}_3 > \mathrm{BiH}_3

B. The reducing ability of the hydride increases in the order NH3<PH3<AsH3<SbH3<BiH3\mathrm{NH}_3 < \mathrm{PH}_3 < \mathrm{AsH}_3 < \mathrm{SbH}_3 < \mathrm{BiH}_3

C. Among the hydrides, NH3\mathrm{NH}_3 is strong reducing agent while BiH3\mathrm{BiH}_3 is mild reducing agent.

D. The basicity of the hydrides increases in the order

NH3<PH3<AsH3<SbH3<BiH3\mathrm{NH}_3 < \mathrm{PH}_3 < \mathrm{AsH}_3 < \mathrm{SbH}_3 < \mathrm{BiH}_3

Choose the most appropriate from the option given below
View answer and explanation
Correct option: B
A and B only
Option B (A and B only) is correct because the stability and reducing ability trends are accurate, while basicity decreases down the group and NH3 is not a strong reducing agent.

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