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NEET UG CHEMISTRY MCQ: CHEMICAL KINETICS

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Analyzing +4 | -1
The inversion of cane sugar proceeds with half-life of 500 minute at pH=5\mathrm{pH}=5 for any concentration of sugar. However, if pH=6,\mathrm{pH}=6, the half-life changes to 50 minute. The rate law expression for the sugar inversion can be written as
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Correct option: D
r=K[sugar][H+]−1r=K[\text{sugar}]\left[\mathrm{H}^{+}\right]^{-1}
The correct answer is D (r=K[sugar][H+]−1r=K[\text {sugar}][\mathrm{H}^{+}]^{-1}) because the half-life is inversely proportional to the hydrogen ion concentration, indicating a negative first-order dependence on [H+].

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