NEET UG CHEMISTRY MCQ: ALCOHOLS & PHENOLS & ETHERS

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Which will gives turbidity rapidly on reaction with Lucas reagent

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Correct option: D

C{H_3} - \mathop {\mathop {C}\limits^{\mathop {C{H_3}}\limits_| } }\limits_{\mathop {OH}\limits^| } - C{H_3}

Option D (

C{H_3} - \mathop {\mathop {C}\limits^{\mathop {C{H_3}}\limits_|} }\limits_{\mathop {OH}\limits^| } - C{H_3}

) is correct because Lucas reagent reacts fastest with tertiary alcohols due to the formation of a more stable tertiary carbocation intermediate.

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{\text{C}}{{\text{H}}_3}{\text{C}}{{\text{H}}_2}{\text{OH}}\xrightarrow{{{\text{PCC}}}}{\text{A}}\xrightarrow[{\left( {{\text{ii}}} \right){\text{ }}{{\text{H}}_2}{\text{O/}}{{\text{H}}^ + }}]{{\left( {\text{i}} \right){\text{ HCN}}}}{\text{B}}

\mathrm{O}_2

{\mathrm{P}_2}{\mathrm{S}_5}