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NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Analyzing +4 | -1
At 298 K, the standard electrode potentials of Cu2+/Cu,Zn2+/Zn,Fe2+/Fe  and  Ag+/AgC{u^{2 + }}/Cu,Z{n^{2 + }}/Zn,F{e^{2 + }}/Fe\,\,\mathrm{and}\,\,A{g^ + }/Ag are 0.34 V, - 0.76 V, - 0.44 V and 0.80 V, respectively.
On the basis of standard electrode potential, predict which of the following reaction cannot occur?
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Correct option: A
2CuSO4(aq)+2Ag(s)→2Cu(s)+Ag2SO4(aq)2CuS{O_4}(aq) + 2Ag(s) \to 2Cu(s) + A{g_2}S{O_4}(aq)
Option A (2CuSO4(aq)+2Ag(s)→2Cu(s)+Ag2SO4(aq)2CuS{O_4}(aq) + 2Ag(s) \to 2Cu(s) + A{g_2}S{O_4}(aq)) is correct because the cell potential for this reaction is negative, indicating it is non-spontaneous.

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