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NEET UG CHEMISTRY MCQ: Equilibrium

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Analyzing +4 | -1
A solution is 0.1 M in Cl−C{l^ - } and 0.001 M in CrO42−CrO_4^{2 - }. Solid AgNO3AgN{O_3} is gradually added to it. Assuming that the addition does not change in volume and Ksp(AgCl)=1.7×10−10 M2{K_{sp}}(AgCl) = 1.7 \times {10^{ - 10}}\,{M^2} and Ksp(Ag2CrO4)=1.9×10−12 M3{K_{sp}}(A{g_2}Cr{O_4}) = 1.9 \times {10^{ - 12}}\,{M^3}
Select correct statement from the following
View answer and explanation
Correct option: D
AgClAgCl will precipitate first as the amount of Ag+A{g^ + } needed to precipitate is low.
Option D (AgClAgCl will precipitate first as the amount of Ag+A{g^ + } needed to precipitate is low) is correct because it requires a lower concentration of Ag+Ag^+ to reach the KspK_{sp} for AgClAgCl compared to Ag2CrO4Ag_2CrO_4.

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