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JEE CHEMISTRY MCQ: CHEMICAL BONDING & MOLECULAR STRUCTURE

1 Easy
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Analyzing +4 | -1
Assertion (A): All P−ClP-Cl bond lengths are equal in PCl3{PCl}_3 but different in PCl5.{PCl}_5.

Reason (R): Hybrid state of central atom is different in Both molecules.
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Correct option: B
Both (A) & (R) are true but the (R) is not the correct explanation of the (A)
Option B (Both (A) & (R) are true but the (R) is not the correct explanation of the (A)) is correct because both the assertion and the reason are true, but the reason does not explain the assertion. The difference in bond lengths in PCl5{PCl}_5 is due to axial and equatorial positions, not just the hybridization.

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