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NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

1 Hard
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Analyzing +4 | -1
MnO4−+8H++5e−→Mn2++4H2O;E∘=1.51V\mathrm{MnO}_4^ - + 8{\mathrm{H}^ + } + 5{e^ - } \to \mathrm{M}{\mathrm{n}^{2 + }} + 4{\mathrm{H}_2}\mathrm{O};{E^ \circ } = 1.51\mathrm{V}

MnO4+4H++2e−→Mn2++2H2O;E∘=1.23V\mathrm{Mn}{\mathrm{O}_4} + 4{\mathrm{H}^ + } + 2{e^ - } \to \mathrm{M}{\mathrm{n}^{2 + }} + 2{\mathrm{H}_2}\mathrm{O};{E^ \circ } = 1.23\mathrm{V}

EMnO4−∣MnO2∘E_{\mathrm{MnO}_4^ - |\mathrm{Mn}{\mathrm{O}_2}}^ \circ is
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Correct option: A
1.70 V
Option A (1.70 V) is correct because it is calculated by combining the given half-reactions to obtain the desired half-reaction and using the relationship between Gibbs free energy and standard potential.

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