JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

1 Medium

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Analyzing +4 | -1

Assertion (A) : The reaction

\mathrm{XeO}_3+6 \mathrm{H}^{+}+6 e^{-} \rightleftharpoons \mathrm{Xe}+3 \mathrm{H}_2 \mathrm{O}, E^{\circ}=2.1 \mathrm{~V}

is not feasible thermodynamically to oxidise

\mathrm{H}_2 \mathrm{O}

Reason (R) : There is a high activation energy barrier between oxidation state +6 and 0 of

\mathrm{Xe}

View answer and explanation

Correct option: C

\mathbf{A}

is true but

\mathbf{R}

is false.

Option C is correct. Assertion (A) is true because

XeO_3

is a strong oxidizing agent with a high reduction potential. Reason (R) is false because the kinetics of the reaction, not a high activation energy barrier, prevents it from oxidizing water readily.

More Questions from P-BLOCK ELEMENTS

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The gas used for inflating the tyres of aeroplanes is: Which of the following is correct stability order of oxides of

17^{\text {th }}

group elements is: Assertion: Ozone is a powerful oxidising agent in comparison to

{O}_2

.

Reason: Ozone is diamagnetic but

{O}_2

is paramagnetic. Which of the following is kept in water?

\mathrm{C}{\mathrm{N}^ - }

ion and

{\mathrm{N}_2}

are isoelectronic but in contrast to

\mathrm{C}{\mathrm{N}^ - },\mathrm{\;}{\mathrm{N}_2}

is chemically inert because of: Consider the following statements

(i) Reaction

2 {Fe}^{3+}+{SO}_2+2 {H}_2 {O} \rightarrow 2 {Fe}^{2+}+{SO}_4^{2-}+4 {H}^{+}

shows reducing character of sulphur dioxide

(ii)

{H}_2 {~S}_2 {O}_8

contains four

{S}={O}

, two

{S}-{OH}

and one

{O}-

{O}

bond

(iii)

{NH}_3

gas can be dried effectively by using conc.

{H}_2 {SO}_4

.

(iv) One of the major use of

{H}_2 {SO}_4

is in the manufacture of fertilizers.

Which of the following is the correct code for the statements above?