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NEET UG CHEMISTRY MCQ: Equilibrium

1 Easy
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Application +4 | -1
At a given temperature the Kc{K_c} for the reaction, PCl5(g)  ⇋  PCl3(g)+Cl2(g)\mathrm{PC}{\mathrm{l}_5}\left( \mathrm{g} \right)\;\leftrightharpoons\;\mathrm{PC}{\mathrm{l}_3}\left( \mathrm{g} \right) + \mathrm{C}{\mathrm{l}_2}\left( \mathrm{g} \right) is 2.4×10−32.4 \times {10^{ - 3}}. At the same temperature, the Kc{K_c} for the reaction

PCl3(g)+Cl2(g)  ⇋  PCl5(g)\mathrm{PC}{\mathrm{l}_3}\left( \mathrm{g} \right) + \mathrm{C}{\mathrm{l}_2}\left( \mathrm{g} \right)\;\leftrightharpoons\;\mathrm{PC}{\mathrm{l}_5}\left( \mathrm{g} \right) is :
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Correct option: C
4.2×10−24.2 \times {10^{ - 2}}
Option C is correct because the second reaction is the reverse of the first, so its equilibrium constant is the inverse of the first: Kc' = 1/Kc = 1/(2.4 × 10-3) = 416.67. However, the provided answer is incorrect. The correct answer should be approximately 416.67, which is not among the options.

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