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JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Analyzing +4 | -1
Assertion (A) : Cl2{Cl}_2 or Br2{Br}_2 changes KI{KI} into I2{I}_2 (violet in CCl4{CCl}_4 layer), Cl2{Cl}_2 changes KBr{KBr} into Br2{Br}_2 (orange-yellow in CCl4{CCl}_4 layer). Thus, Cl2{Cl}_2 would change mixture of KI{KI} and KBr{KBr} into violet layer in CCl4{CCl}_4.

Reason (R) : Oxidising power is in order I2<Br2<Cl2<F2{I}_2 < {Br}_2 < {Cl}_2 < {F}_2.
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Correct option: A
Both A\mathbf{A} and R\mathbf{R} are true and R\mathbf{R} is the correct explanation of A\mathbf{A}.
Option A (Both A and R are true and R is the correct explanation of A) is correct because chlorine is a stronger oxidizing agent than bromine, which is stronger than iodine, thus chlorine will oxidize both iodide and bromide to their respective halogens.

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