NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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Analyzing +4 | -1

Which method can be used to distinguish

\left[{Co}\left({NH}_3\right)_6\right]\left[{Cr}\left({NO}_2\right)_6\right]

and

\left[{Cr}\left({NH}_3\right)_6\right]\left[{Co}\left({NO}_2\right)_6\right]

View answer and explanation

Correct option: D

By electrolysis of their aqueous solutions.

Option D is correct because the two complexes will yield different ions upon electrolysis, leading to different conductivity changes.

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\left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;}

\left[\mathrm{Cr}(\mathrm{Ox})_{2} \mathrm{ClBr}\right]^{3-}

\text{ox =}

x

{\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right]^x}

\mathrm{M}{\mathrm{n}^{2 + }}

\mathrm{CuS}{\mathrm{O}_4}

{\mathrm{K}_2}\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right]