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JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Assertion (A) : Both H3PO3\mathrm{H}_3 \mathrm{PO}_3 and H3PO4\mathrm{H}_3 \mathrm{PO}_4 have the same number of hydrogen atoms but H3PO4\mathrm{H}_3 \mathrm{PO}_4 is a tribasic acid and H3PO3\mathrm{H}_3 \mathrm{PO}_3 is a dibasic acid.

Reason (R) : 1 mole of H3PO3\mathrm{H}_3 \mathrm{PO}_3 is neutralised by 2 moles of NaOH\mathrm{NaOH} while 1 mole of H3PO4\mathrm{H}_3 \mathrm{PO}_4 is neutralised by 3 moles of NaOH\mathrm{NaOH}.
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Correct option: B
Both A\mathbf{A} and R\mathbf{R} are true but R\mathbf{R} is not the correct explanation of A\mathbf{A}.
Option B (Both A\mathbf{A} and R\mathbf{R} are true but R\mathbf{R} is not the correct explanation of A\mathbf{A}) is correct because both the assertion and the reason are true statements, but the reason doesn't directly explain why H3PO3\mathrm{H}_3\mathrm{PO}_3 is dibasic and H3PO4\mathrm{H}_3\mathrm{PO}_4 is tribasic.

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