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NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Analyzing +4 | -1
Following cell has EMF 0.7995 V0.7995 \mathrm{~V}.

Pt∣H2(1 atm)∣HNO3(1M)∥AgNO3(1M)∣Ag\mathrm{Pt}\left|\mathrm{H}_2(1 \mathrm{~atm})\right| \mathrm{HNO}_3(1 \mathrm{M}) \| \mathrm{AgNO}_3(1 \mathrm{M}) \mid \mathrm{Ag}

If we add enough KCl\mathrm{KCl} to the Ag\mathrm{Ag} cell so that the
final Cl−\mathrm{Cl}^{-}is 1M1 \mathrm{M}. Now the measured emf of the cell is 0.222 V0.222 \mathrm{~V}. The Ksp\mathrm{K}_{s p} of AgCl\mathrm{AgCl} would be-
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Correct option: A
1×10−9.81 \times 10^{-9.8}
Option A (1×10−9.81 \times 10^{-9.8}) is correct because it is calculated using the Nernst equation and the change in EMF to find the concentration of Ag+Ag^+ and then the KspK_{sp} of AgClAgCl.

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