NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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Palladium complexes of the type

\left[ {Pd{{\left( {{C_6}{H_5}} \right)}_2}{{\left( {SCN} \right)}_2}} \right]

and

\left[ {Pd{{\left( {{C_6}{H_5}} \right)}_2}{{\left( {NCS} \right)}_2}} \right]

are

View answer and explanation

Correct option: A

Linkage isomers

Option A is correct because

\left[ {Pd{{\left( {{C_6}{H_5}} \right)}_2}{{\left( {SCN} \right)}_2}} \right]

and

\left[ {Pd{{\left( {{C_6}{H_5}} \right)}_2}{{\left( {NCS} \right)}_2}} \right]

differ in the mode of attachment of the

SCN^-

ligand, exhibiting linkage isomerism.

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\left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;}

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\text{ox =}

x

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