NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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Which one of the following will not show geometrical isomerism?

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Correct option: C

\left[ {\mathrm{Co}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_5}\mathrm{N}{\mathrm{O}_2}} \right]\mathrm{C}{\mathrm{l}_2}

Option C is correct because

\left[ {\mathrm{Co}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_5}\mathrm{N}{\mathrm{O}_2}} \right]\mathrm{C}{\mathrm{l}_2}

does not have different spatial arrangements of ligands around the central metal atom.

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\left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;}

\left[\mathrm{Cr}(\mathrm{Ox})_{2} \mathrm{ClBr}\right]^{3-}

\text{ox =}

x

{\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right]^x}

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\mathrm{CuS}{\mathrm{O}_4}

{\mathrm{K}_2}\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right]