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NEET UG CHEMISTRY MCQ: ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES AND TECHNIQUES

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Analyzing +4 | -1
(i) F3C−COOH\mathrm{F}_3 \mathrm{C}-\mathrm{COOH}

(ii) CH3−COOH\mathrm{CH}_3-\mathrm{COOH}

(iii) C6H5−COOH\mathrm{C}_6 \mathrm{H}_5-\mathrm{COOH}

(iv) CH3CH2COOH\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH}

Correct order of pKa\mathrm{pK}_{\mathrm{a}} value is:
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Correct option: B
iv >> ii >> iii >> i
Option B (iv > ii > iii > i) is correct because the pKa value increases with decreasing acidity. Electron-withdrawing groups increase acidity, thus decreasing pKa.

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