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NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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Understanding +4 | -1
Assertion (A): The electronic absorption spectrum of the tetrahedral complex, [CoCl4]2−\left[{CoCl}_4\right]^{2-} shows bands which are more intense compared to the absorption bands for the octahedral complex [Co(H2O)6]2+\left[{Co}\left({H}_2 {O}\right)_6\right]^{2+}.

Reason (R) : The octahedral complexes possess a centre of symmetry.
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Correct option: B
Both A\mathbf{A} and R\mathbf{R} are true but R\mathbf{R} is not the correct explanation of A\mathbf{A}.
Option B (Both A\mathbf{A} and R\mathbf{R} are true but R\mathbf{R} is not the correct explanation of A\mathbf{A}) is correct because both the assertion and the reason are true statements, but the reason (presence of a center of symmetry in octahedral complexes) does not explain why tetrahedral complexes have more intense absorption bands.

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