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NEET UG CHEMISTRY MCQ: 13 TH GROUP ELEMENTS (P-BLOCK)

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Analyzing +4 | -1
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) In TlI3Tl{I_3}, isomorphous to CsI3Cs{I_3}, the metal is present in + 1 oxidation state.
Reason (R) TlTl metal has fourteen f−f -electrons in the electronic configuration.
In the light of the above statements, choose the most appropriate answer from the options given below.
View answer and explanation
Correct option: B
Both A and R are correct and R is the correct explanation of A.
Option A is correct because Tl in TlI3 exists as Tl+ and I3- due to the inert pair effect, and the presence of 14 f-electrons contributes to this effect.

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