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NEET UG CHEMISTRY MCQ: CHEMICAL KINETICS

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Analyzing +4 | -1
For the reaction, N2O5→2NO2+12O2{\mathrm{N}_2}{\mathrm{O}_5} \to 2\mathrm{N}{\mathrm{O}_2} + \frac{1}{2}{\mathrm{O}_2}

Given, −d[N2O5]dt=K1[N2O5]- \frac{{d\left[ {{\mathrm{N}_2}{\mathrm{O}_5}} \right]}}{{dt}} = {K_1}\left[ {{\mathrm{N}_2}{\mathrm{O}_5}} \right]

d[NO2]dt=K2[N2O5]\frac{{d\left[ {\mathrm{N}{\mathrm{O}_2}} \right]}}{{dt}} = {K_2}\left[ {{\mathrm{N}_2}{\mathrm{O}_5}} \right]

and    d[O2]dt=K3[N2O5]\mathrm{and}\;\;\frac{{d\left[ {{\mathrm{O}_2}} \right]}}{{dt}} = {K_3}\left[ {{\mathrm{N}_2}{\mathrm{O}_5}} \right]

The relation in between K1,K2  and  K3{K_1},{K_2}\;and\;{K_3} is:
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Correct option: A
2K1=K2=4K32{K_1} = {K_2} = 4{K_3}
Option A (2K1=K2=4K32{K_1} = {K_2} = 4{K_3}) is correct because it correctly relates the rate constants based on the stoichiometry of the reaction.

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