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NEET UG CHEMISTRY MCQ: CHEMICAL KINETICS

1 Hard
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Analyzing +4 | -1
For a gaseous reaction A(g)→Products (order=n),\mathrm{A}(\mathrm{g}) \rightarrow \text{Products (order} = n), the rate may be expressed as

(i) −dPAdt=K1⋅PAn-\frac{\mathrm{d} P_{\mathrm{A}}}{\mathrm{d} t}=K_1 \cdot P_{\mathrm{A}}^n

(ii) −1VdnAdt=K2⋅CAn-\frac{1}{V} \frac{\mathrm{d} n_{\mathrm{A}}}{\mathrm{d} t}=K_2 \cdot C_{\mathrm{A}}^n

The rate constants, K1K_1 and K2K_2 are related as (PA\left(P_{\mathrm{A}}\right. and CAC_{\mathrm{A}} are the partial pressures and molar concentration of A\text{A} at time 'tt', respectively)
View answer and explanation
Correct option: D
K2=K1⋅(RT)n−1K_2=K_1 \cdot(R T)^{n-1}
Option D (K2=K1⋅(RT)n−1K_2=K_1 \cdot(R T)^{n-1}) is correct because it correctly relates the rate constants K1K_1 and K2K_2 based on the ideal gas law and the order of the reaction.

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