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JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Analyzing +4 | -1

Assertion (A): The gas phase reaction,

\mathrm{PCl}_3(\mathrm{~g})+\mathrm{Cl}_2(\mathrm{~g}) \rightleftharpoons \mathrm{PCl}_5(\mathrm{~g}) ; \Delta \mathrm{H}=-32.8 \mathrm{~k~cal} \mathrm{~mol}^{-1}

shifts to the right direction on increasing temperature.

Reason (R): When temperature increases, equilibrium shifts towards right for an endothermic reaction.

View answer and explanation

Correct option: D

Assertion (A) is false, but Reason (R) is true

Option D is correct because the assertion is false, as increasing temperature shifts the equilibrium to the left for an exothermic reaction, while the reason is true.

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The gas used for inflating the tyres of aeroplanes is: Which of the following is correct stability order of oxides of

17^{\text {th }}

group elements is: Assertion: Ozone is a powerful oxidising agent in comparison to

{O}_2

.

Reason: Ozone is diamagnetic but

{O}_2

is paramagnetic. Which of the following is kept in water?

\mathrm{C}{\mathrm{N}^ - }

{\mathrm{N}_2}

are isoelectronic but in contrast to

\mathrm{C}{\mathrm{N}^ - },\mathrm{\;}{\mathrm{N}_2}

is chemically inert because of: Consider the following statements

(i) Reaction

2 {Fe}^{3+}+{SO}_2+2 {H}_2 {O} \rightarrow 2 {Fe}^{2+}+{SO}_4^{2-}+4 {H}^{+}

shows reducing character of sulphur dioxide

(ii)

{H}_2 {~S}_2 {O}_8

{S}={O}

{S}-{OH}

{O}-

{O}

{NH}_3

gas can be dried effectively by using conc.

{H}_2 {SO}_4

.

(iv) One of the major use of

{H}_2 {SO}_4

is in the manufacture of fertilizers.

Which of the following is the correct code for the statements above?