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NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

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Understanding +4 | -1
STATEMENT-1 : If (dEcell dT)p>0\left(\frac{d E_{\text {cell }}}{d T}\right)_p>0 for a cell reaction then ΔS\Delta S is positive.

STATEMENT-2 : ΔS=nFT(dEdT)p\Delta S=n F T\left(\frac{d E}{d T}\right)_p
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Correct option: C
If STATEMENT-1 is TRUE and STATEMENT-2 is FALSE
Statement-1 is TRUE: If (dEcell/dT)_p > 0, then ΔS is positive because ΔG = -nFEcell and ΔG = ΔH - TΔS. Statement-2 is FALSE: The correct relation is ΔS = nF(dE/dT)_p.

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