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JEE CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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The IUPAC name of K3[Ir⁡(C2O4)3]\mathrm{K}_3\left[\operatorname{Ir}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right] is
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Correct option: B
potassium trioxalatoiridate (III)
Option D (potassium tris (oxalato) iridate (III)) is correct because it follows IUPAC nomenclature rules for coordination compounds, naming the cation first, then the ligand alphabetically with appropriate prefixes, and ending with the metal name with its oxidation state in Roman numerals and \"-ate\" suffix because the complex is an anion.

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Which has maximum paramagnetic character? Ionization of K[Ag(CN)2]\mathrm{K}\left[ {\mathrm{Ag}{{\left( {\mathrm{CN}} \right)}_2}} \right] will give: The cation that does not form an ammine complex with excess of ammonia is: The complexes [PtCl2(NH3)4]Br2  and  [PtBr2(NH3)4]Cl2  \left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;} are example for isomerism The correct name of [Pt(NH3)4Cl2][PtCl4]\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\left[\mathrm{PtCl}_4\right] is: Which of the following pairs of isomers and types of isomerism are correctly matched?

(I) [Co(NH3)5(NO2)]Cl2\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2 and [Co(NH3)5(ONO)]Cl2………\left[{Co}\left({NH}_3\right)_5({ONO})\right] {Cl}_2 \ldots \ldots \ldots Linkage

(II) [Cu(NH3)4][PtCl4]  &  [Pt(NH3)4][CuCl4]………\left[{Cu}\left({NH}_3\right)_4\right]\left[{PtCl}_4\right] \,\, \& \,\, \left[{Pt}\left({NH}_3\right)_4\right]\left[{CuCl}_4\right] \ldots \ldots \ldots Coordinations

(III) [Pt(NH3)4Cl2]Br2  &  [Pt(NH3)4Br2]Cl2………\left[{Pt}\left({NH}_3\right)_4 {Cl}_2\right] {Br}_2 \, \, \& \, \, \left[{Pt}\left({NH}_3\right)_4 {Br}_2\right]{Cl}_2 \ldots \ldots \ldots Ionization

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