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JEE CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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The correct name of [Pt(NH3)4Cl2][PtCl4]\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\left[\mathrm{PtCl}_4\right] is:
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Correct option: A
Tetraammine dichloro platinum (IV) tetrachloro platinate (II)
Option A (Tetraammine dichloro platinum (IV) tetrachloro platinate (II)) is correct because it follows the IUPAC naming conventions for coordination compounds, where the cation is named before the anion, ligands are named alphabetically, and oxidation states are indicated in Roman numerals.

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Which has maximum paramagnetic character? Ionization of K[Ag(CN)2]\mathrm{K}\left[ {\mathrm{Ag}{{\left( {\mathrm{CN}} \right)}_2}} \right] will give: The cation that does not form an ammine complex with excess of ammonia is: The complexes [PtCl2(NH3)4]Br2  and  [PtBr2(NH3)4]Cl2  \left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;} are example for isomerism Which of the following pairs of isomers and types of isomerism are correctly matched?

(I) [Co(NH3)5(NO2)]Cl2\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2 and [Co(NH3)5(ONO)]Cl2………\left[{Co}\left({NH}_3\right)_5({ONO})\right] {Cl}_2 \ldots \ldots \ldots Linkage

(II) [Cu(NH3)4][PtCl4]  &  [Pt(NH3)4][CuCl4]………\left[{Cu}\left({NH}_3\right)_4\right]\left[{PtCl}_4\right] \,\, \& \,\, \left[{Pt}\left({NH}_3\right)_4\right]\left[{CuCl}_4\right] \ldots \ldots \ldots Coordinations

(III) [Pt(NH3)4Cl2]Br2  &  [Pt(NH3)4Br2]Cl2………\left[{Pt}\left({NH}_3\right)_4 {Cl}_2\right] {Br}_2 \, \, \& \, \, \left[{Pt}\left({NH}_3\right)_4 {Br}_2\right]{Cl}_2 \ldots \ldots \ldots Ionization

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Which of the following is a pair of diamagnetic complex?
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