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NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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Understanding +4 | -1
Which of the following sets is/are example(s) of co-ordination isomerism is complex?
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Correct option: A
[Co(NH3)6][Cr(CN)6]\left[{Co}\left({NH}_3\right)_6\right][{Cr}({CN})_6] and [Co(CN6)][Cr(NH3)6]\left[{Co}\left({CN}_6\right)\right]\left[{Cr}\left({NH}_3\right)_6\right]
Option A is correct because [Co(NH3)6][Cr(CN)6]\left[{Co}\left({NH}_3\right)_6\right][{Cr}({CN})_6] and [Co(CN6)][Cr(NH3)6]\left[{Co}\left({CN}_6\right)\right]\left[{Cr}\left({NH}_3\right)_6\right] involve the exchange of ligands between the cationic and anionic coordination entities.

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The complexes [PtCl2(NH3)4]Br2  and  [PtBr2(NH3)4]Cl2  \left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;} are example for isomerism The total number of stereoisomers for the complex [Cr(Ox)2ClBr]3−\left[\mathrm{Cr}(\mathrm{Ox})_{2} \mathrm{ClBr}\right]^{3-} (where ox =\text{ox =} oxalate) is The value of xx on the [Ni(CN)4]x{\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right]^x} is: Excited state configuration of Mn2+\mathrm{M}{\mathrm{n}^{2 + }} is CuSO4\mathrm{CuS}{\mathrm{O}_4} decolourises on addition of KCN, the product is: The IUPAC name of K2[Ni(CN)4]{\mathrm{K}_2}\left[ {\mathrm{Ni}{{\left( {\mathrm{CN}} \right)}_4}} \right] is
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