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NEET UG CHEMISTRY MCQ: Equilibrium

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H2S{\mathrm{H}_2}\mathrm{S} is passed into one dm3\mathrm{d}{\mathrm{m}^3} of a solution containing 0.1  mole  of  Zn3  and  0.01  mole  of  Cu20.1\;\mathrm{mole}\;\mathrm{ of }\;\mathrm{Z}{\mathrm{n}^3}\mathrm{ \;and}\;0.01\;\mathrm{mole }\;\mathrm{of}\;\mathrm{ C}{\mathrm{u}^2}  till the sulphide ion concentration reaches 8.1  ×  10108.1\; \times \;{10^{10}} moles. Which one of the following statements is true? [Ksp{K_{\mathrm{sp}}} of Zn\mathrm{Zn} and CuS\mathrm{CuS} are  3  ×1022  and  8  ×1036\mathrm{are}\;3\; \times {10^{22}}\;\mathrm{and}\;8\; \times {10^{36}} respectively]
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Correct option: B
Both  CuS  and  ZnS  precipitates\mathrm{Both}\;\mathrm{CuS }\;\mathrm{and }\;\mathrm{ZnS }\;\mathrm{precipitates}
Option B (Both  CuS  and  ZnS  precipitates\mathrm{Both}\;\mathrm{CuS }\;\mathrm{and }\;\mathrm{ZnS }\;\mathrm{precipitates}) is correct because the ionic product for both CuSCuS and ZnSZnS exceeds their respective KspK_{sp} values, causing them to precipitate.

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