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NEET UG CHEMISTRY MCQ: HYDROGEN

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Analyzing +4 | -1
Assertion (A) : Ionisation constant of CH3COOH\mathrm{CH}_3 \mathrm{COOH} and CH3COOD\mathrm{CH}_3 \mathrm{COOD} are very equal.

Reason (R): The kinetic isotopic effect is not observed in the ionisation of weak acid.
View answer and explanation
Correct option: D
A\mathbf{A} and R\mathbf{R} both are false
Option D (A\mathbf{A} and R\mathbf{R} both are false) is correct because the ionization constants of CH3COOH\mathrm{CH}_3\mathrm{COOH} and CH3COOD\mathrm{CH}_3\mathrm{COOD} are slightly different due to the kinetic isotopic effect, and this effect is observed in the ionization of weak acids.

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