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JEE CHEMISTRY MCQ: P-BLOCK ELEMENTS

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Analyzing +4 | -1
Assertion (A): (NH4)2Cr2O7,\left(\mathrm{NH}_4\right)_2 \mathrm{Cr}_2 \mathrm{O}_7, on heating doesn't form any residue.

Reason (R): In Cr2O72−\mathrm{Cr}_2 \mathrm{O}_7^{2-} there are six equivalent Cr−O\mathrm{Cr}-\mathrm{O} bonds.
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Correct option: D
Both (A) and (R) are false
Option D is correct because both the assertion and the reason are false. Ammonium dichromate on heating leaves a residue of Cr2O3, and the Cr-O bonds in dichromate are not all equivalent.

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