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NEET UG CHEMISTRY MCQ: CHEMICAL KINETICS

1 Hard
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Analyzing +4 | -1
The reaction of hydrogen and iodine monochloride is given as:

H2( g)+2ICl(g)⟶2HCl(g)+I2( g){H}_2({~g})+2 {ICl}({g}) \longrightarrow 2 {HCl}({g})+{I}_2({~g})

The reaction is of first order with respect to H2( g){H}_2({~g}) and ICI(g){ICI}({g}), following mechanisms were proposed.

Mechanism A:

H2( g)+2ICl(g)⟶2HCl(g)+I2( g){H}_2({~g})+2 {ICl}({g}) \longrightarrow 2 {HCl}({g})+{I}_2({~g})

Mechanism B:

H2( g)+ICl(g)⟶HI(g); slow HI(g)+ICl(g)⟶HCl(g)+I2( g); fast \begin{aligned} & {H}_2({~g})+{ICl}({g}) \longrightarrow {HI}({g}) ; \text { slow } \\ & {HI}({g})+{ICl}({g}) \longrightarrow {HCl}({g})+{I}_2({~g}) ; \text { fast } \end{aligned}

Which of the above mechanism(s) can be consistent with the given information about the reaction?
View answer and explanation
Correct option: D
B only
The correct answer is D (B only) because mechanism B's slow step matches the given rate law, while mechanism A does not.

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