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NEET UG CHEMISTRY MCQ: THERMODYNAMICS

1 Hard
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Analyzing +4 | -1
Given,

KOH(aq)+HCl(aq)⟶KCl(aq)+H2O(l);ΔH=−57.3 kJ mol−1…(i)\mathrm{KOH}(\mathrm{aq})+\mathrm{HCl}(\mathrm{aq}) \longrightarrow \mathrm{KCl}(\mathrm{aq})+\mathrm{H}_2 \mathrm{O}(l); \Delta H=-57.3 \mathrm{~kJ} \mathrm{~mol}^{-1} \ldots (i)

H2( g)+12O2( g)⟶H2O(l);ΔH=−286.2 kJ mol−1….....(ii)\mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g}) \longrightarrow \mathrm{H}_2 \mathrm{O}(\mathrm{l}); \Delta \mathrm{H}=-286.2 \mathrm{~kJ} \mathrm{~mol}^{-1} \ldots.....(ii)

12H2( g)+12Cl2( g)→AqHCl(aq);ΔH=−164.4 kJ mol−1…(iii)\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{Cl}_2(\mathrm{~g}) \xrightarrow{A q} \mathrm{HCl}(\mathrm{aq}); \Delta H=-164.4 \mathrm{~kJ} \mathrm{~mol}^{-1} \ldots(\mathrm{iii)}

K(s)+12O2( g)+12H2( g)+aq⟶KOH(aq);ΔH=−487.4 kJ mol−1…(iv)\mathrm{K}(\mathrm{s})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})+\frac{1}{2} \mathrm{H}_2(\mathrm{~g})+\mathrm{aq} \longrightarrow \mathrm{KOH}(\mathrm{aq}) ; \Delta H=-487.4 \mathrm{~kJ} \mathrm{~mol}^{-1} \ldots(\mathrm{iv})

KCl(s)+aq⟶KCl(aq);ΔH=+18.4 kJ mol−1\mathrm{KCl}(\mathrm{s})+\mathrm{aq} \longrightarrow \mathrm{KCl}(\mathrm{aq}); \Delta H=+18.4 \mathrm{~kJ} \mathrm{~mol}{ }^{-1}.....(v)

Heat of formation of KCl\mathrm{KCl} will be
View answer and explanation
Correct option: B
−441.3 kJ mol−1-441.3 \mathrm{~kJ} \mathrm{~mol}^{-1}
Option B is correct because the heat of formation of KCl can be calculated by manipulating the given equations using Hess's Law.

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