Skip to main content
Back to ELECTRO CHEMISTRY

NEET UG CHEMISTRY MCQ: ELECTRO CHEMISTRY

1 Hard
1 of 1
Analyzing +4 | -1
For the following half-cell reactions, E∘E^{\circ} values are:

Mn2+(aq)+2H2O(l)⟶MnO2( s)+4H+(aq)+2e−;E∘=−123 VMnO4−(aq)+4H+(aq)+3e−⟶MnO2( s)+2H2O(l);E∘=+1.70 V\begin{aligned} & \mathrm{Mn}^{2+}(\mathrm{aq})+2 \mathrm{H}_2 \mathrm{O}(l) \longrightarrow \mathrm{MnO}_2(\mathrm{~s})+4 \mathrm{H}^{+}(\mathrm{aq})+2 \mathrm{e}^{-} ; E^{\circ}=-123 \mathrm{~V} \\ & \mathrm{MnO}_4^{-}(\mathrm{aq})+4 \mathrm{H}^{+}(\mathrm{aq})+3 \mathrm{e}^{-} \longrightarrow \mathrm{MnO}_2(\mathrm{~s})+2 \mathrm{H}_2 \mathrm{O}(l) ; E^{\circ}=+1.70 \mathrm{~V} \end{aligned}
Thus,
View answer and explanation
Correct option: C
MnO2\mathrm{MnO}_2 disproportionates to Mn2+\mathrm{Mn}^{2+} and MnO4−\mathrm{MnO}_4^{-}in acid solution
Option C is correct because the given reduction potentials indicate that MnO2 can be reduced to Mn2+ and oxidized to MnO4- in acidic solution, thus disproportionating.

More Questions from ELECTRO CHEMISTRY

Practice All Chapter MCQs →
Type at least 2 characters or jump directly:
🔓

Save your learning progress

Sign in with a free account to save your practice answers and quiz results, then return to them when you revise.