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NEET UG CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

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On treatment of 100 mL of 0.1 M solution of COCl3.6H2OCOC{l_3}.6{H_2}O with excess of AgNO3; 1.2×1022AgN{O_3};\,1.2 \times {10^{22}} ions are precipitated. The complex is
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Correct option: D
[Co(H2O)5Cl]Cl2.H2O\left[ {Co{{\left( {{H_2}O} \right)}_5}Cl} \right]C{l_2}.{H_2}O
Option D ([Co(H2O)5Cl]Cl2.H2O\left[ {Co{{\left( {{H_2}O} \right)}_5}Cl} \right]C{l_2}.{H_2}O) is correct because it corresponds to the precipitation of 2 chloride ions per complex molecule, matching the given ion precipitation data.

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