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NEET UG CHEMISTRY MCQ: Equilibrium

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Analyzing +4 | -1
The following equilibrium constants were determined at 1120 K1120 {~K} :
2CO(g)⇌C(s)+CO2( g);Kp1=10−14 atm−1CO(g)+Cl2(g)⇌COCl2( g);Kp2=6×10−3 atm−1\begin{aligned} & 2 {CO}(g) \rightleftharpoons {C}({s})+{CO}_2({~g}) ; K_{p_1} =10^{-14} {~atm}^{-1} \\ & {CO}(g)+{Cl}_2(g) \rightleftharpoons {COCl}_2({~g}) ; K_{p_2} =6 \times 10^{-3} {~atm}^{-1} \end{aligned}
What is the equilibrium constant KcK_c for the following reaction at 1120 K1120 {~K} :
C(s)+CO2( g)+2Cl2( g)⇌2COCl2( g){C}({s})+{CO}_2({~g})+2 {Cl}_2({~g}) \rightleftharpoons 2 {COCl}_2({~g})
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Correct option: A
3.31×1011M−13.31 \times 10^{11} {M}^{-1}
Option A (3.31×1011M−13.31 \times 10^{11} {M}^{-1}) is correct because it is calculated by manipulating the given equilibrium constants and converting KpK_p to KcK_c using the ideal gas law.

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