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NEET • CHEMISTRY • POLYMERS
Polymers practice · Medium
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Showing 1-30 of 48 questions
1
Medium
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Analyzing
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Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation
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Correct option: B
III > II > I
Option B (III > II > I) is correct because electron-donating groups enhance cationic polymerization, while electron-withdrawing groups hinder it.
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Understanding
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Assertion: Vulcanisation of rubber increases its tensile strength.
Reason: Sulphur cross links are formed between poly-isoprene chains during vulcanisation.
Reason: Sulphur cross links are formed between poly-isoprene chains during vulcanisation.
View answer and explanation
Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
Option A (Both assertion and reason are correct statements, and reason is the correct explanation of the assertion) is correct because vulcanization increases tensile strength due to the formation of sulfur cross-links between the polyisoprene chains.
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Understanding
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Which of the following is not an example of addition polymer?
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Correct option: A
Terylene
Option A (Terylene) is correct because Terylene (polyethylene terephthalate) is a condensation polymer, not an addition polymer.
4
Medium
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Remembering
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Whether small molecules liberate in addition
polymerisation?
polymerisation?
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Correct option: B
No
Option B (No) is correct because addition polymerization involves the direct addition of monomers without the elimination of any small molecules.
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Medium
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Understanding
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Which of the following is a condensation polymer?
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Correct option: D
Polyethylene terephthalate
Option D (Polyethylene terephthalate) is correct because it is formed through a condensation reaction between ethylene glycol and terephthalic acid.
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Medium
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Understanding
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Which of the following is not an example of a condensation polymer?
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Correct option: C
Buna- N
Option C (Buna- N) is correct because Buna-N is an addition polymer, not a condensation polymer.
7
Medium
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Understanding
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Which one of the following statement is wrong?
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Correct option: B
Dibenzol peroxide is a catalyst in the polymerization of PVC.
Option B (Dibenzol peroxide is a catalyst in the polymerization of PVC) is wrong because dibenzoyl peroxide is a catalyst for the polymerization of many alkenes, but not specifically for PVC. PVC uses other catalysts for its polymerization.
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Medium
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Analyzing
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Assertion :- When a rubber band is stretched entropy increases.
Reason :- During expansion entropy increases.
Reason :- During expansion entropy increases.
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Correct option: D
If both Assertion & Reason are False
Option D (If both Assertion & Reason are False) is correct because when a rubber band is stretched, entropy decreases, and the reason provided is too general.
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Medium
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Understanding
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Which of the following vinyl derivatives is most reactive towards anionic polymerisation?
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Correct option: D
Option D () is correct because the presence of the electron-withdrawing cyano group activates the vinyl group towards nucleophilic attack in anionic polymerization.
10
Medium
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Understanding
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In which of the following polymers, empirical formula resembles with monomer?
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Correct option: B
Teflon
Option B (Teflon) is correct because the empirical formula of Teflon () is the same as its monomer, tetrafluoroethylene ().
11
Medium
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Understanding
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Consider following statements
I. Cationic polymerization occurs in monomers with electron donation substitutents.
II. Anionic polymerization occurs in monomers with electron-withdrawing substitutents.
III. Head-to-head chain growth polymerisation occurs in polystyrene
Select correct statements
I. Cationic polymerization occurs in monomers with electron donation substitutents.
II. Anionic polymerization occurs in monomers with electron-withdrawing substitutents.
III. Head-to-head chain growth polymerisation occurs in polystyrene
Select correct statements
View answer and explanation
Correct option: A
I,II
Option A (I,II) is correct because cationic polymerization is favored by electron-donating substituents, and anionic polymerization is favored by electron-withdrawing substituents.
12
Medium
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Understanding
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Assertion: HDP has lesser flexibility than LDP.
Reason: LDP has a more branched structure than HDP.
Reason: LDP has a more branched structure than HDP.
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Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
Option A (Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.) is correct because HDP has a more linear structure, resulting in less flexibility compared to LDP, which has branching.
13
Medium
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Remembering
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Natural rubber is polymer of
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Correct option: A
Cis – polyisoprene
Option A (Cis – polyisoprene) is correct because natural rubber is a polymer of cis-isoprene units.
14
Medium
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Understanding
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Assertion: Benzoyl peroxide is necessary for free radical polymerisation.
Reason: Peroxides give the necessary free radicals required for initiating the polymerisation process.
Reason: Peroxides give the necessary free radicals required for initiating the polymerisation process.
View answer and explanation
Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
Option A (Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.) is correct because benzoyl peroxide decomposes to generate free radicals that initiate the polymerization process.
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Remembering
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Which among the following is a homopolymer?
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Correct option: B
Neoprene
Option B is correct because Neoprene is a polymer made from a single type of monomer (chloroprene), making it a homopolymer.
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Medium
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Understanding
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A copolymer is obtained by polymerisation of:
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Correct option: B
More than one type of monomer units
Option B (More than one type of monomer units) is correct because a copolymer is, by definition, formed from the polymerization of two or more different types of monomers.
17
Medium
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Analyzing
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Two condensation polymers are made
(1) ethylene diamine + ethane-1,2-dicarboxylic acid
(2) trimethylenediamine + ethane-1,2-dicarboxylic acid if both polymers of same molecular weight are obtained then which of the following statements is/are correct?
(i) Polymer (1) is found to melt at lower temperature.
(ii) Polymer (2) is found to melt at lower temperature.
(iii) H-bonding is major factor.
(1) ethylene diamine + ethane-1,2-dicarboxylic acid
(2) trimethylenediamine + ethane-1,2-dicarboxylic acid if both polymers of same molecular weight are obtained then which of the following statements is/are correct?
(i) Polymer (1) is found to melt at lower temperature.
(ii) Polymer (2) is found to melt at lower temperature.
(iii) H-bonding is major factor.
View answer and explanation
Correct option: D
(ii) and (iii)
Option D ((ii) and (iii)) is correct because polymer (2) has weaker intermolecular forces due to the longer alkyl chain, leading to a lower melting temperature, and H-bonding is a major factor in condensation polymers.
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Medium
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Understanding
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Chloroprene is obtained by addition of HCI to
View answer and explanation
Correct option: C
Vinylacetylene
Option C (Vinylacetylene) is correct because chloroprene (2-chloro-1,3-butadiene) is formed by the addition of HCl to vinylacetylene.
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Remembering
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Of the following which is a step growth polymer?
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Correct option: A
Bakelite
Option A (Bakelite) is correct because Bakelite is formed through a step-growth polymerization process involving condensation reactions.
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Medium
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Understanding
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Thermosets are:
View answer and explanation
Correct option: D
All of the above
Option D (All of the above) is correct because thermosets are cross-linked polymers that do not melt or soften upon heating, and their cross-linking is usually developed during moulding.
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Medium
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Remembering
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An example of natural biopolymer is
View answer and explanation
Correct option: D
DNA
Option D is correct because DNA is a naturally occurring polymer composed of nucleotide monomers.
22
Medium
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Remembering
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Among the following polymers the strongest molecular forces are present in
View answer and explanation
Correct option: D
thermosetting polymers
Option B (fibres) is correct because fibres have the strongest intermolecular forces due to their highly ordered structure and strong hydrogen bonding.
23
Medium
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Remembering
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Which of the following polymers of glucose is stored by animals?
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Correct option: D
Glycogen
Option D (Glycogen) is correct because glycogen is the storage form of glucose in animals.
24
Medium
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Remembering
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Which one of the following polymers may be classified as step growth polymer?
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Correct option: D
Nylon 66
Option D (Nylon 66) is correct because Nylon 66 is formed through a step-growth polymerization mechanism.
25
Medium
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Remembering
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Among the following, the wrong statement is
View answer and explanation
Correct option: B
SBR is natural rubber
Option B is correct because SBR (Styrene-Butadiene Rubber) is a synthetic rubber, not natural rubber.
26
Medium
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Remembering
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A polymer containing nitrogen is
View answer and explanation
Correct option: D
Nylon-66
Option D is correct because Nylon-66 contains nitrogen atoms in its amide linkages.
27
Medium
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Remembering
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Which of the following rubber is not a polydiene?
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Correct option: C
Thiokol rubber
Option C (Thiokol rubber) is correct because Thiokol rubber is a polysulfide rubber, not a polydiene.
28
Medium
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Remembering
+4 | -1
Example of addition polymer is:
View answer and explanation
Correct option: A
Buna-S
Option A (Buna-S) is correct because Buna-S is formed by the addition polymerization of butadiene and styrene.
29
Medium
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Application
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The number average molecular mass and mass average molecular mass of a polymer are respectively 30,000 and 40,000. The poly dispersity index of the polymer is
View answer and explanation
Correct option: B
> 1
Option B (> 1) is correct because the polydispersity index (PDI) is the ratio of mass average molecular mass to number average molecular mass, and for polymers, this value is always greater than 1.
30
Medium
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Remembering
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Salicylic acid, aspirin, nylon, plastics and picric acid have a common raw material, namely:
View answer and explanation
Correct option: C
Phenol
Option C (Phenol) is correct because phenol is a common raw material in the synthesis of salicylic acid, aspirin, nylon, plastics (like Bakelite), and picric acid.
Revision notes and key takeaways
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Key Takeaways
- ✓ This set contains 48 single-correct-answer MCQs on POLYMERS.
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