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NEET • CHEMISTRY • Equilibrium

Equilibrium practice · Medium

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91 Medium
91 of 146
Understanding +4 | -1
Which among the following is an electron deficient compound?
View answer and explanation
Correct option: C
BF3\mathrm{B}{\mathrm{F}_3}
Option C (BF3\mathrm{BF_3}) is correct because Boron in BF3 has only 6 electrons in its valence shell, making it electron deficient.
92 Medium
92 of 146
Understanding +4 | -1
A solution of sodium borate has a pH\mathrm{pH} of approximately:
View answer and explanation
Correct option: A
>7> 7
Option A (>7> 7) is correct because sodium borate is the salt of a weak acid and a strong base, resulting in a basic solution with a pHpH greater than 7.
93 Medium
93 of 146
Application +4 | -1
One litre of water contains 10−7  mole  H+{10^{ - 7}}\;\mathrm{mole}\;{\mathrm{H}^ + } ions. Degree of ionisation of water is:
View answer and explanation
Correct option: A
1.8×10−7  %1.8 \times {10^{ - 7}}\;\%
Option B is correct because the degree of ionization is calculated by dividing the concentration of H+ ions by the initial concentration of water and multiplying by 100 to express it as a percentage.
94 Medium
94 of 146
Application +4 | -1
If the pressure of N2/H2{\mathrm{N}_2}/{\mathrm{H}_2} mixture in a closed apparatus is 100 atm and 20%20\% of the mixture then reacts, the pressure at the same temperature would be :
View answer and explanation
Correct option: B
90
The correct answer is B (90) because the pressure decreases due to the stoichiometry of the reaction, resulting in fewer moles of gas.
95 Medium
95 of 146
Understanding +4 | -1
In the reaction, 3A+2B→2C3A + 2B \to 2C, the equilibrium constant Kc{K_c} is given by
View answer and explanation
Correct option: C
[C]2[A]3×[B]2\frac{{{{\left[ C \right]}^2}}}{{{{\left[ A \right]}^3} \times {{\left[ B \right]}^2}}}
Option C is correct because the equilibrium constant is the ratio of products to reactants, each raised to the power of their stoichiometric coefficients.
96 Medium
96 of 146
Remembering +4 | -1
The concept that an acid is a proton donor and a base is a proton acceptor was introduced by:
View answer and explanation
Correct option: B
Bronsted-Lowry
Option B (Bronsted-Lowry) is correct because the Bronsted-Lowry definition of acids and bases states that acids are proton donors and bases are proton acceptors.
97 Medium
97 of 146
Analyzing +4 | -1
The equilibrium,

P4(s)+6Cl2(g)  ⇋  4PCl3(g){\mathrm{P}_4}\left( s \right) + 6\mathrm{C}{\mathrm{l}_2}\left( \mathrm{g} \right)\;\leftrightharpoons\;4\mathrm{PC}{\mathrm{l}_3}\left( \mathrm{g} \right) attained by mixing equal moles of P4{\mathrm{P}_4} and Cl2\mathrm{C}{\mathrm{l}_2} in a evacuated vessel. Then, at equilibrium,
View answer and explanation
Correct option: C
[P4]>[Cl2]\left[ {{\mathrm{P}_4}} \right] > \left[ {\mathrm{C}{\mathrm{l}_2}} \right]
Option C ([P₄] > [Cl₂]) is correct because according to the stoichiometry of the reaction, 6 moles of Cl₂ react with 1 mole of P₄. Since equal moles were initially mixed, Cl₂ will be consumed to a greater extent.
98 Medium
98 of 146
Understanding +4 | -1
An aqueous solution of 1M  NaCl  and  1  M  HCl  is\mathrm{1M }\;\mathrm{NaCl}\;\mathrm{ and}\;1\;\mathrm{M}\;\mathrm{ HCl }\;\mathrm{is}
View answer and explanation
Correct option: A
not  a  buffer  but  pH<7\mathrm{not\; a\; buffer\; but\; pH} < 7
Option A (not a buffer but pH < 7) is correct because a mixture of a strong acid (HCl) and a neutral salt (NaCl) will result in a solution with a low pH and no buffering capacity.
99 Medium
99 of 146
Application +4 | -1
The pH\mathrm{pH} of 10−8M  HCl{10^{ - 8}}\mathrm{M\; HCl} solution is
View answer and explanation
Correct option: C
Between 6 and 7
Option C (Between 6 and 7) is correct because at very low concentrations of acid, the contribution of water's autoionization becomes significant, preventing the pH from reaching 8.
100 Medium
100 of 146
Remembering +4 | -1
Arrange the following in increasing order of solubility product:

Ca(OH)2,AgBr,PbS,HgS\mathrm{Ca}(\mathrm{OH})_2, \mathrm{AgBr}, \mathrm{PbS}, \mathrm{HgS}
View answer and explanation
Correct option: B
HgS<PbS<AgBr<Ca(OH)2\mathrm{HgS}< \mathrm{PbS}< \mathrm{AgBr}< \mathrm{Ca}(\mathrm{OH})_2
Option B (HgS < PbS < AgBr < Ca(OH)2) is correct because it represents the increasing order of their solubility product values.
101 Medium
101 of 146
Understanding +4 | -1
When pressure is applied to the equilibrium system ice r water. Which of the following phenomenon will happen?
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Correct option: C
More water will be formed
Option C (More water will be formed) is correct because increasing pressure favors the side with the smaller volume, which is water in this case.
102 Medium
102 of 146
Understanding +4 | -1
Which one of the following salts on being dissolved in water gives pH  >  7  at  25∘C\mathrm{pH}\; > \;7\;\mathrm{at}\;25^\circ C
View answer and explanation
Correct option: A
KCN\mathrm{KCN}
Option A (KCN) is correct because KCN is a salt of a strong base (KOH) and a weak acid (HCN), so it will undergo hydrolysis to produce a basic solution with pH > 7.
103 Medium
103 of 146
Remembering +4 | -1
van′t  Hoff′s\mathrm{va}{\mathrm{n}^\mathrm{'}}\mathrm{t }\;\mathrm{Hoff's} equation giving the effect of temperature on chemical equilibrium is represented as:
View answer and explanation
Correct option: C
d  In  KpdT=ΔHRT2\frac{{d\;\mathrm{In}\;{K_p}}}{{dT}} = \frac{{\Delta H}}{{R{T^2}}}
Option C (d  In  KpdT=ΔHRT2\frac{{d\;\mathrm{In}\;{K_p}}}{{dT}} = \frac{{\Delta H}}{{R{T^2}}}) is correct because this is the correct form of the van't Hoff equation, relating the change in the equilibrium constant with temperature to the enthalpy change.
104 Medium
104 of 146
Analyzing +4 | -1
Final pressure is higher than initial pressure of a container filled with an ideal gas at constant temperature. What will be the value of equilibrium constant?
View answer and explanation
Correct option: D
K<1.0K < 1.0
Option D (K<1.0K < 1.0) is correct because if the final pressure is higher than the initial pressure at constant temperature, it means the reaction favors the side with more moles of gas, indicating that the equilibrium constant is less than 1.
105 Medium
105 of 146
Understanding +4 | -1
The pH of pure water at 500C{50^0}C is
View answer and explanation
Correct option: C
Less than 7
Option C (Less than 7) is correct because the autoionization of water increases with temperature, leading to a higher concentration of both H+ and OH- ions, but neutrality is still maintained, resulting in a pH less than 7.
106 Medium
106 of 146
Remembering +4 | -1
A solution that has reserve acidity (or) alkalinity is called
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Correct option: C
Buffer solution
Option C (Buffer solution) is correct because a buffer solution is specifically designed to resist changes in pH by having reserve acidity or alkalinity.
107 Medium
107 of 146
Understanding +4 | -1
In a vessel containing SO3, SO2,\mathrm{S}{\mathrm{O}_3},\,\mathrm{S}{\mathrm{O}_2}, and O2{\mathrm{O}_2} at equilibrium, some helium gas in introduced so that, the total pressure increase, while temperature and volume remain constant. According to Le-Chatelier’s principle the dissociation of SO3:\mathrm{S}{\mathrm{O}_3}:
View answer and explanation
Correct option: C
Remains unaltered
Option C (Remains unaltered) is correct because the addition of an inert gas at constant volume does not affect the partial pressures of the reactants and products, thus the equilibrium remains unchanged.
108 Medium
108 of 146
Understanding +4 | -1
Which of the following is correct for the reaction?
N2(g)+3H2(g)⇋2NH3(g){\mathrm{N}_2}\left( \mathrm{g} \right) + 3{\mathrm{H}_2}\left( \mathrm{g} \right)\leftrightharpoons2\mathrm{N}{\mathrm{H}_3}\left( \mathrm{g} \right)
View answer and explanation
Correct option: B
Kp<Kc{K_p} < {K_c}
Option B is correct because for the given reaction, Δn < 0, which implies Kp < Kc.
109 Medium
109 of 146
Application +4 | -1
5 moles of SO2  \mathrm{S}{\mathrm{O}_2}\; and 5 moles of O2  {\mathrm{O}_2}\; are allowed to react to forms SO3\mathrm{S}{\mathrm{O}_3} in a closed vessel. At the equilibrium stage 60% of SO2  \mathrm{S}{\mathrm{O}_2}\; is used up. The total number of moles of   SO2  ,O2  and  SO3\;\mathrm{S}{\mathrm{O}_2}\;,{\mathrm{O}_2}\;and\;\mathrm{S}{\mathrm{O}_3} in the vessel now is
View answer and explanation
Correct option: A
8.58.5
Option A (6.08×10−66.08 \times {10^{ - 6}}) is correct because the overall formation constant is the product of the individual stepwise formation constants.
110 Medium
110 of 146
Understanding +4 | -1
In the hydrolysis of a salt of weak acid and weak base, the hydrolysis constant Kh{K_h} is equal to
View answer and explanation
Correct option: C
KwKa.Kb\frac{{{K_w}}}{{{K_a}.{K_b}}}
Option C (KwKa.Kb\frac{{{K_w}}}{{{K_a}.{K_b}}}) is correct because the hydrolysis constant for a salt of a weak acid and weak base is given by this formula.
111 Medium
111 of 146
Application +4 | -1
Partial pressure of A,B,CA,B,C and DD on the basis of gaseous system, A+2B  ⇋  C+3D,A + 2B\;\leftrightharpoons\;C + 3D, are A=0.20,  B=0.10,  C=0.30A = 0.20,\;B = 0.10,\;C = 0.30 and D=0.50  atmD = 0.50\;\mathrm{atm}. The numerical value of equilibrium constant is
View answer and explanation
Correct option: B
18.7518.75
Option B (18.7518.75) is correct because it's the calculated value of the equilibrium constant KpK_p based on the given partial pressures.
112 Medium
112 of 146
Understanding +4 | -1
For the reaction, H2(g)+I2(g)→2HI(g){\mathrm{H}_2}\left( \mathrm{g} \right) + {\mathrm{I}_2}\left( \mathrm{g} \right) \to 2\mathrm{HI}\left( \mathrm{g} \right), the equilibrium constant Kp{K_p} changes with
View answer and explanation
Correct option: D
Temperature
Option D (Temperature) is correct because the equilibrium constant Kp{K_p} is temperature-dependent. Changing the temperature affects the equilibrium position and thus the value of Kp{K_p}.
113 Medium
113 of 146
Remembering +4 | -1
The pHpH of tears coming out of a person’s eye is:
View answer and explanation
Correct option: A
7.47.4
Option A (7.4) is correct because the pH of tears is approximately 7.4, which is slightly basic and similar to the pH of blood.
114 Medium
114 of 146
Application +4 | -1
For the reaction equilibrium,

2NOBr(g)  ⇋  2NO(g)+Br2(g),2\mathrm{NOBr}\left( \mathrm{g} \right)\;\leftrightharpoons\;2\mathrm{NO}\left( \mathrm{g} \right) + \mathrm{B}{\mathrm{r}_2}\left( \mathrm{g} \right), if PBr2=P9{P_{\mathrm{B}{\mathrm{r}_2}}} = \frac{P}{9} at equilibrium and PP is total pressure. The ratio Kp/P{K_p}/P is equal to:
View answer and explanation
Correct option: B
1/811/81
Option B is correct because the Kp/P ratio can be calculated from the given partial pressure of Br2 and the stoichiometry of the reaction.
115 Medium
115 of 146
Analyzing +4 | -1
Which of the following salts is the most basic in aqueous solution?
View answer and explanation
Correct option: B
CH3COOKC{H_3}COOK
Option B (CH3COOKCH_3COOK) is the most basic because it is a salt of a weak acid (CH3COOHCH_3COOH) and a strong base (KOH).
116 Medium
116 of 146
Analyzing +4 | -1
Statement I :SO2(g)+12O2(g)⇌SO2(g)\mathrm{SO}_{2(g)}+\frac{1}{2} \mathrm{O}_{2(g)} \rightleftharpoons S \mathrm{O}_{2(g)}+heat. Forward rection is favoured at high temperature and low pressure.

Statement II : Reaction is endothermic.
View answer and explanation
Correct option: B
Statement I, II are incorrect
Option B (Statement I, II are incorrect) is correct because the forward reaction is favored at low temperature and high pressure, and the reaction is exothermic, not endothermic.
117 Medium
117 of 146
Understanding +4 | -1
A solution of FeCl3\mathrm{FeC}{\mathrm{l}_3} in water acts as acidic due to:
View answer and explanation
Correct option: C
Hydrolysis of Fe3+\mathrm{F}{\mathrm{e}^{3 + }}
Option C (Hydrolysis of Fe3+\mathrm{F}{\mathrm{e}^{3 + }}) is correct because the ferric ion undergoes hydrolysis, releasing H+{\mathrm{H}^ + } ions and making the solution acidic.
118 Medium
118 of 146
Application +4 | -1
The first and second dissociation constants of an acid
H2A are  1.0×10−5 and  5.0×10−10{\mathrm{H}_2}A\,\mathrm{are}\,\,1.0 \times {10^{ - 5}}\,\mathrm{and}\,\,5.0 \times {10^{ - 10}} respectively. The overall dissociation constant of the acid will be
View answer and explanation
Correct option: C
5.0×10−155.0 \times {10^{ - 15}}
Option C (5.0×10−155.0 \times {10^{ - 15}}) is correct because the overall dissociation constant is the product of the individual dissociation constants.
119 Medium
119 of 146
Remembering +4 | -1
If KcK_c is in the range of _____ appreciable concentrations of both reactants and products are present.
View answer and explanation
Correct option: B
10−310^{-3} to 10310^3
Option B (10−310^{-3} to 10310^3) is correct because it indicates that the concentrations of reactants and products are neither overwhelmingly large nor small, allowing for a measurable equilibrium.
120 Medium
120 of 146
Analyzing +4 | -1
Which of the following will have maximum pH?
View answer and explanation
Correct option: C
M10  NaOH\frac{\mathrm{M}}{{10}}\;\mathrm{NaOH}
Option C (M10  NaOH\frac{\mathrm{M}}{{10}}\;\mathrm{NaOH}) is correct because it represents the most concentrated strong base, leading to the highest pH.
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