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NEET • CHEMISTRY • ELECTRO CHEMISTRY

Electro chemistry practice · Medium

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61 Medium
61 of 145
Understanding +4 | -1
Is the reaction, 2Al+3Fe2+→2Al3++3Fe2\mathrm{Al} + 3\mathrm{F}{\mathrm{e}^{2 + }} \to 2\mathrm{A}{\mathrm{l}^{3 + }} + 3\mathrm{Fe} possible?
View answer and explanation
Correct option: B
Yes, because standard oxidation potential of Al>Fe\mathrm{Al} > Fe
Option B is correct because a reaction is possible if the standard oxidation potential of the element being oxidized (Al) is greater than that of the element being reduced (Fe).
62 Medium
62 of 145
Remembering +4 | -1
The value of electronic charge is equal to :
View answer and explanation
Correct option: A
FaradayAv.number\frac{{\mathrm{Faraday}}}{{\mathrm{Av}\mathrm{.}{\kern 1pt} {\kern 1pt} \mathrm{number}}}
Option A is correct because the electronic charge is the total charge of one mole of electrons (Faraday constant) divided by the number of electrons in a mole (Avogadro's number).
63 Medium
63 of 145
Application +4 | -1
E1,E2{E_1},{E_2} , and E3{E_3} are the emfs of the following three galvanic cells respectively
I. Zn (s) |Zn2+Z{n^{2 + }} (1 M) || Cu2+\mathrm{C}{\mathrm{u}^{2 + }} (0.1 M) | Cu (s)
II. Zn (s) |Zn2+Z{n^{2 + }} (1 M) || Cu2+\mathrm{C}{\mathrm{u}^{2 + }} (1 M) | Cu (s)
III. Zn (s) | Zn2+Z{n^{2 + }} (0.1 M) || Cu2+\mathrm{C}{\mathrm{u}^{2 + }} (1 M) | Cu (s)
Which one of the following is true?
View answer and explanation
Correct option: D
E3>E2>E1{E_3} > {E_2} > {E_1}
Option D (E3>E2>E1{E_3} > {E_2} > {E_1}) is correct because, based on the Nernst equation, increasing the concentration of reactants and decreasing the concentration of products increases the cell emf.
64 Medium
64 of 145
Understanding +4 | -1
Which of the following reactions is correct for a given electrochemical cell at 25∘C{25^ \circ }C?

Pt∣Br2(g)∣Br−(g)∣∣Cl−(aq)∣Cl2(g)∣Pt\mathrm{Pt}\left| {\mathrm{B}{\mathrm{r}_2}\left( \mathrm{g} \right)} \right|\mathrm{B}{\mathrm{r}^ - }\left( \mathrm{g} \right)||\mathrm{C}{\mathrm{l}^ - }\left( {aq} \right)\left| {\mathrm{C}{\mathrm{l}_2}\left( \mathrm{g} \right)} \right|\mathrm{Pt}
View answer and explanation
Correct option: A
2Br−(aq)+Cl2(g)→2Cl−(aq)+Br2(g)2\mathrm{B}{\mathrm{r}^ - }\left( {\mathrm{aq}} \right) + \mathrm{C}{\mathrm{l}_2}\left( \mathrm{g} \right) \to 2\mathrm{C}{\mathrm{l}^ - }\left( {\mathrm{aq}} \right) + \mathrm{B}{\mathrm{r}_2}\left( \mathrm{g} \right)
Option A is correct because it represents the spontaneous reaction occurring in the electrochemical cell, where chlorine oxidizes bromide ions.
65 Medium
65 of 145
Application +4 | -1
The hydrogen electrode is dipped in a solution of pH = 3 at 25∘C{25^ \circ }C. The reduction potential of the cell would be :
View answer and explanation
Correct option: B
⎯ 0.177 V
Option B (⎯ 0.177 V) is correct because the reduction potential is calculated using the Nernst equation for the hydrogen electrode at the given pH.
66 Medium
66 of 145
Analyzing +4 | -1
Assertion: When aqueous sodium chloride solution is electrolysed, Oxygen gas is produced at the anode.

Reason: It is due to the overpotential for oxidation of water to oxygen.
View answer and explanation
Correct option: A
Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.
Option A is correct because the assertion and reason are both true, and the overpotential for water oxidation explains why chloride ions are oxidized instead of water at the anode during the electrolysis of aqueous NaCl.
67 Medium
67 of 145
Application +4 | -1
EMF of hydrogen electrode in term of pH is (at 1 atm pressure)
View answer and explanation
Correct option: D
EH2={E_{{H_2}}} = - 0.0591 pH
Option D (EH2={E_{{H_2}}} = - 0.0591 pH) is correct because it directly relates the EMF of a hydrogen electrode to the pH of the solution at 1 atm pressure.
68 Medium
68 of 145
Remembering +4 | -1
Indicator electrode is :
View answer and explanation
Correct option: D
Quinhydrone electrode
Option D is correct because a quinhydrone electrode is a type of redox electrode used as an indicator electrode to measure hydrogen ion concentration (pH).
69 Medium
69 of 145
Analyzing +4 | -1
Cu(II)\mathrm{Cu}\left( {\mathrm{II}} \right) sulphate solution is treated separately with KCl\mathrm{KCl} and KI. In which case, Cu2+\mathrm{C}{\mathrm{u}^{2 + }} be reduced to Cu+?\mathrm{C}{\mathrm{u}^ + }?
View answer and explanation
Correct option: B
With KI
Option B (With KI) is correct because I- is a stronger reducing agent than Cl-, and Cu2+ is reduced to Cu+ by I-.
70 Medium
70 of 145
Analyzing +4 | -1
Equal quantities of electricity are passed through three voltameters containing FeSO4,Fe2(SO4)3\mathrm{FeSO}_4, \mathrm{Fe}_2\left(\mathrm{SO}_4\right)_3, and Fe(NO3)3\mathrm{Fe}\left(\mathrm{NO}_3\right)_3. Consider the following statements in this regard:
(1) The amount of iron deposited in FeSO4\mathrm{FeSO}_4 and Fe2(SO4)3\mathrm{Fe}_2\left(\mathrm{SO}_4\right)_3 is equal
(2) The amount of iron deposited in Fe(NO3)3\mathrm{Fe}\left(\mathrm{NO}_3\right)_3 is two thirds of the amount of iron deposited in FeSO4\mathrm{FeSO}_4
(3) The amount of iron deposited in Fe2(SO4)3 Fe(NO3)3\mathrm{Fe}_2\left(\mathrm{SO}_4\right)_3\,\mathrm{Fe}\left(\mathrm{NO}_3\right)_3 is equal
Of these statements:
View answer and explanation
Correct option: B
2 and 3 are correct
Option B (2 and 3 are correct) is correct because the amount of iron deposited depends on the charge required to deposit one mole of iron, and statements 2 and 3 accurately reflect the ratios of iron deposited in the different compounds.
71 Medium
71 of 145
Remembering +4 | -1
Which of the following chemical reactions represents Hall-Heroult Process?
View answer and explanation
Correct option: B
2Al2O3+3C→4Al+3CO22A{l_2}{O_3} + 3C \to 4Al + 3C{O_2}
Option B (2Al2O3+3C→4Al+3CO22Al_2O_3 + 3C \to 4Al + 3CO_2) is the correct representation of the Hall-Heroult process, which is used for aluminum extraction.
72 Medium
72 of 145
Remembering +4 | -1
The standard electrode potential is measured by
View answer and explanation
Correct option: B
Voltmeter
Option B (Voltmeter) is correct because a voltmeter is the instrument used to measure the potential difference, which includes standard electrode potential.
73 Medium
73 of 145
Analyzing +4 | -1
Assertion (A) Ecell E_{\text {cell }} increases with increase in concentration of Ag+\mathrm{Ag}^{+}ions.

Reason (R) Ecell E_{\text {cell }} has positive value.
View answer and explanation
Correct option: B
Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Option B is correct because both the assertion and reason are true, but the reason does not explain the assertion. The Nernst equation explains the effect of concentration on cell potential.
74 Medium
74 of 145
Understanding +4 | -1
Which of the following aqueous solution will have the maximum specific conductance?
View answer and explanation
Correct option: A
0.1 HCl
Option A (0.1 HCl) is correct because HCl is a strong acid and provides the highest concentration of highly mobile H+ ions, leading to maximum specific conductance.
75 Medium
75 of 145
Application +4 | -1
How much charge is present on 3 grams of CO32−CO_3^{2 - } ions?
View answer and explanation
Correct option: B
9650 C
Option B is correct. The charge is calculated by finding the number of moles of carbonate ions and then multiplying by the charge per mole of ions (2F).
76 Medium
76 of 145
Remembering +4 | -1
Which of the following is the use of electrolysis?
View answer and explanation
Correct option: C
Both (1) &\& (2)
Option C (Both (1) & (2)) is correct because electrolysis is used in both electrorefining and electroplating.
77 Medium
77 of 145
Understanding +4 | -1
The products formed when an aqueous solution of NaBr{NaBr} is electrolysed in a cell having inert electrodes are:
View answer and explanation
Correct option: C
H2,Br2{H}_2, {Br}_2 and NaOH{NaOH}
Option C (H2,Br2{H}_2, {Br}_2 and NaOH{NaOH}) is correct because during the electrolysis of aqueous NaBr, water is reduced at the cathode to produce hydrogen gas and hydroxide ions, while bromide ions are oxidized at the anode to produce bromine gas.
78 Medium
78 of 145
Understanding +4 | -1
Which process involves corrosion?
View answer and explanation
Correct option: D
All of the above
Option D (All of the above) is correct because all the listed processes (brown deposits on iron, green deposits on battery terminals, and black deposits on silver) are examples of corrosion.
79 Medium
79 of 145
Remembering +4 | -1
Which is the correct relationship between equilibrium constant and standard reduction potential of cell?
View answer and explanation
Correct option: B
Ecell0=0.059nlog⁡KcE_{\text {cell}}^0=\frac{0.059}{n} \log K_c
Option B (Ecell0=0.059nlog⁡KcE_{\text {cell}}^0=\frac{0.059}{n} \log K_c) is the correct relationship between the standard cell potential and the equilibrium constant at 298 K.
80 Medium
80 of 145
Remembering +4 | -1
Galvanization is applying a coating of:
View answer and explanation
Correct option: C
ZnZn
Option C (ZnZn) is correct because galvanization is the process of coating iron or steel with zinc to protect it from corrosion.
81 Medium
81 of 145
Application +4 | -1
One mole of electrons passes through each of the solution of AgNO3, CuSO4AgN{O_3},\,CuS{O_4} and AlCl3AlC{l_3} when Ag,CuAg,Cu and AlAl are deposited at cathode. The molar ratio of Ag,Cu  and AlAg,Cu\,\,\mathrm{and}\,Al deposited are
View answer and explanation
Correct option: B
6:3:26:3:2
Option B (6:3:2) is correct because it reflects the molar ratio of Ag, Cu, and Al deposited based on their respective valencies and the passage of one mole of electrons.
82 Medium
82 of 145
Application +4 | -1
ECu∘=0.34V,EZn∘=0.76VE_{Cu}^ \circ = 0.34V,E_{Zn}^ \circ = 0.76V . A Daniel cell contains 0.1 M ZnSO4\mathrm{ZnS}{\mathrm{O}_4} solution and 0.01 M CuSO4\mathrm{CuS}{\mathrm{O}_4} solution at its electrodes. EMF of the cell is
View answer and explanation
Correct option: A
1.10 V
Option A (1.10 V) is correct because, under standard conditions (and close enough to it), the EMF of the Daniel cell is approximately the difference between the standard reduction potentials of copper and zinc.
83 Medium
83 of 145
Application +4 | -1
The equivalent conductivity of KCl\mathrm{KCl} at infinite dilution is 130 mhocm2eq−1{\rm{mho {\kern 1pt} {\kern 1pt}c}}{\mathrm{m}^2}{\kern 1pt} {\kern 1pt}\mathrm{e}{\mathrm{q}^{ - 1}}. The transport number of Cl−\mathrm{C}{\mathrm{l}^ - } ion in KCl\mathrm{KCl} at the same temperature is 0.505. The transport number of K+{\mathrm{K}^ + } ion is :
View answer and explanation
Correct option: A
0.495
Option A (0.495) is correct because the sum of the transport numbers of the cation and anion in an electrolyte solution must equal 1.
84 Medium
84 of 145
Analyzing +4 | -1
The number of electrons transferred (lost or gained) during the reactions Fe+H2O→Fe3O4+H2Fe + {H_2}O \to F{e_3}{O_4} + {H_2}
View answer and explanation
Correct option: A
8
Option A (8) is correct because the oxidation state of Fe changes from 0 to +8/3, and the total number of electrons transferred is 8.
85 Medium
85 of 145
Analyzing +4 | -1
Assertion: On increasing dilution, the specific conductance keep on increasing.

Reason: On increasing dilution, degree of ionisation ofweak electrolyte increases and molality of ions also increases.
View answer and explanation
Correct option: D
If both the Assertion and Reason are incorrect.
Option D is correct because on increasing dilution, specific conductance decreases, and while the degree of ionization increases, the molality of ions decreases.
86 Medium
86 of 145
Remembering +4 | -1
In mercury cell electrolyte used is
View answer and explanation
Correct option: B
Paste of KOH{KOH} and ZnO{ZnO}
Option B (Paste of KOH{KOH} and ZnO{ZnO}) is correct because this mixture serves as the electrolyte in a mercury cell.
87 Medium
87 of 145
Understanding +4 | -1
For cell reaction,

Zn+Cu2+→Zn2++Cu\mathrm{Zn} + \mathrm{C}{\mathrm{u}^{2 + }} \to \mathrm{Z}{\mathrm{n}^{2 + }} + \mathrm{Cu}

Cell representation is
View answer and explanation
Correct option: A
Zn∣Zn2+∣∣Cu2+∣Cu\mathrm{Zn}\left| {\mathrm{Z}{\mathrm{n}^{2 + }}} \right|\left| {\mathrm{C}{\mathrm{u}^{2 + }}} \right|\mathrm{Cu}
Option A (Zn∣Zn2+∣∣Cu2+∣Cu\mathrm{Zn}\left| \mathrm{Z}{\mathrm{n}^{2 + }} \right|\left| \mathrm{C}{\mathrm{u}^{2 + }} \right|\mathrm{Cu}) is correct because it correctly represents the cell notation with the anode on the left and the cathode on the right.
88 Medium
88 of 145
Understanding +4 | -1
When lead accumulator is charged, it is :
View answer and explanation
Correct option: A
An electrolytic cell
Option A (An electrolytic cell) is correct because when a lead accumulator is charged, electrical energy is used to drive a non-spontaneous chemical reaction.
89 Medium
89 of 145
Understanding +4 | -1
On the basis of electrochemical theory of aqueous corrosion, the reaction occurring at the cathode is
View answer and explanation
Correct option: A
O2(g)+4H+(aq)+4e−→2H2O(l){\mathrm{O}_2}\left( \mathrm{g} \right) + 4{\mathrm{H}^ + }\left( {aq} \right) + 4{e^ - } \to 2{\mathrm{H}_2}\mathrm{O}\left( l \right)
Option A is correct because it represents the reduction of oxygen at the cathode in the electrochemical corrosion process.
90 Medium
90 of 145
Understanding +4 | -1
Faraday's law of electrolysis are related to the
View answer and explanation
Correct option: C
equivalent mass of the electrolyte
Option C (equivalent mass of the electrolyte) is correct because Faraday's laws directly relate the mass of a substance deposited or liberated during electrolysis to the equivalent mass of the electrolyte.
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